Lithium Diffusion & Magnetism in Battery Cathode Material LixNi1/3Co1/3Mn1/3O2
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A detailed characterization of the time scales and mechanisms by which RNA molecules change their folding structure upon binding of metabolites or during catalysis is important for the understanding of the different biological functions of RNA. The folding ...
12-Metallacrown-3 complexes were formed by self-assembly of organometallic half-sandwich complexes [(π-ligand)MCl2]2 (M = Ru, Rh, Ir) and 3-hydroxy-2-pyridone ligands in the presence of Cs2CO3 as base. Upon mixing of different macrocycles, reversible metal ...
This article is part of the project to model the kinetics of high-temperature combustions, occurring behind shock waves and in detonation waves. The "conventional" semi-empirical correlations of ignition delays have been reformulated, by keeping the Arrhen ...
Lithium is widely used in psychotherapy. The Li-6 isotope has a long intrinsic longitudinal relaxation time T-1 on the order of minutes, making it an ideal candidate for hyperpolarization experiments. In the present study we demonstrated that lithium-6 can ...
A future fusion reactor will use deuterium and tritium as fuel. The former is found in abundance in seawater, while the latter is not available naturally due to its short lifetime. Present developments in the context of fusion propose generating tritium in ...
This thesis deals with a laboratory study of heterogeneous reactions involving bromine and chlorine containing reservoir species on alkali salt substrates which are relevant to the marine boundary layer, and on ice substrates which are relevant to the lowe ...
The reaction of half-sandwich complexes of ruthenium, rhodium, and iridium with amino-substituted 3-hydroxy-2-pyridone ligands in aqueous solution gives monomeric O,O'-chelate complexes. Upon addition of base, the complexes assemble to form trimeric metall ...
By implementing new NMR methods that were designed to map very slow exchange processes we have investigated and characterized the refolding kinetics of a thermodynamically stable 34mer RNA sequence in dynamic equilibrium. The RNA sequence was designed to u ...
The dynamic range, sensitivity and dark decay of holographic recording in LiNbO3 crystals doped with 0.2 atomic% Mn with different oxidation states have been measured. The sensitivity is 0.5 cm/J and found to be independent of the oxidation states, while t ...
Electrochem. insertion of lithium in nanoporous and CVD samples of anatase was studied by chronoamperometry. The currents following cathodic and anodic potential steps were monitored as a function of film thickness, temp., and electrolyte concn. The time d ...