Characterization of Solid-Liquid Interfaces with High-Resolution Atomic Force Microscop
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Polyoxometalates (POMs) are desirable in materials applications ranging from uses as catalysts in selective oxidn. reactions to mol.-like building blocks for the prepn. of new extended solids. Using an unprecedented approach involving high temp., molten sa ...
Solid-liquid interfaces play a fundamental role in surface electrochemistry(1), catalysis(2), wetting(3), self-assembly(4) and biomolecular functions(5). The interfacial energy determines many of the properties of such interfaces, including the arrangement ...
Highly ordered organic-inorganic mesostructured material containing regularly distributed phenols is synthesized by combining a direct synthesis of the functional material and a protection-deprotection strategy and characterized at a molecular level throug ...
The achievement of high ionic conductivity in new "polymeric ionic liquids" (PILs) is of great interest as it refers to the solid state electrolytes and their applications in electrochemistry. Four ionic monomers, including two new ones, namely N-[(2-metha ...
An extensive redistribution of spin density in TBrPP-Co molecules adsorbed on a Cu(111) surface is investigated by monitoring Kondo resonances at different locations on single molecules. Remarkably, the width of the Kondo resonance is found to be much larg ...
Imagine a small integrated biomedical analysis laboratory, connected to your home computer, which would be capable of diagnosing illnesses, a lack of vitamins, or the over-presence of substances from samples of blood, urine or saliva. This hypothetic syste ...
Theoretical simulations are particularly well suited to investigate, at a molecular level, direct and indirect effects of ionising radiations in DNA, as in the particular case of irradiation by swift heavy ions such as those used in hadron therapy. In the ...
Hydrolytic: cleavage of the oligopeptides Ace-Ala-Lys-Tyr-Gly similar to Gly-Met-Ala-Ala-Arg-Ala and Ace-Lys-Gly-Gly-Ala-Gly similar to Pro-Met-Ala-Ala-Arg-Gly by Pd(H2O)(4) was theoretically investigated by using molecular dynamics simulations and q ...
Interaction forces between silica surfaces with adsorbed poly (amidoamine) (PAMAM) dendrimers were measured with the colloidal probe technique based on the atomic force microscope (AFM). At small separations, attractive non-DLVO forces are observed. These ...
Humic substances (HS) play an important role in the reactivity and transport of colloids in natural environments. In particular, the presence of fulvic acids (FA) in natural waters modifies the interactions between inorg. particles and biopolymers and make ...