Sonogashira couplingThe Sonogashira reaction is a cross-coupling reaction used in organic synthesis to form carbon–carbon bonds. It employs a palladium catalyst as well as copper co-catalyst to form a carbon–carbon bond between a terminal alkyne and an aryl or vinyl halide. R1: aryl or vinyl R2: arbitrary X: I, Br, Cl or OTf The Sonogashira cross-coupling reaction has been employed in a wide variety of areas, due to its usefulness in the formation of carbon–carbon bonds.
Ekpyrotic universeThe ekpyrotic universe (ˌɛkpaɪˈrɒtɪk) is a cosmological model of the early universe that explains the origin of the large-scale structure of the cosmos. The model has also been incorporated in the cyclic universe theory (or ekpyrotic cyclic universe theory), which proposes a complete cosmological history, both the past and future. The original ekpyrotic model was introduced by Justin Khoury, Burt Ovrut, Paul Steinhardt and Neil Turok in 2001.
Expansion of the universeThe expansion of the universe is the increase in distance between gravitationally unbound parts of the observable universe with time. It is an intrinsic expansion; the universe does not expand "into" anything and does not require space to exist "outside" it. To any observer in the universe, it appears that all but the nearest galaxies (which are bound by gravity) recede at speeds that are proportional to their distance from the observer, on average.
Conformal cyclic cosmologyConformal cyclic cosmology (CCC) is a cosmological model in the framework of general relativity and proposed by theoretical physicist Roger Penrose. In CCC, the universe iterates through infinite cycles, with the future timelike infinity (i.e. the latest end of any possible timescale evaluated for any point in space) of each previous iteration being identified with the Big Bang singularity of the next. Penrose popularized this theory in his 2010 book Cycles of Time: An Extraordinary New View of the Universe.
Initial conditionIn mathematics and particularly in dynamic systems, an initial condition, in some contexts called a seed value, is a value of an evolving variable at some point in time designated as the initial time (typically denoted t = 0). For a system of order k (the number of time lags in discrete time, or the order of the largest derivative in continuous time) and dimension n (that is, with n different evolving variables, which together can be denoted by an n-dimensional coordinate vector), generally nk initial conditions are needed in order to trace the system's variables forward through time.
Quantum field theoryIn theoretical physics, quantum field theory (QFT) is a theoretical framework that combines classical field theory, special relativity, and quantum mechanics. QFT is used in particle physics to construct physical models of subatomic particles and in condensed matter physics to construct models of quasiparticles. QFT treats particles as excited states (also called quanta) of their underlying quantum fields, which are more fundamental than the particles.
Dark energyIn physical cosmology and astronomy, dark energy is an unknown form of energy that affects the universe on the largest scales. The first observational evidence for its existence came from measurements of supernovas, which showed that the universe does not expand at a constant rate; rather, the universe's expansion is accelerating. Understanding the universe's evolution requires knowledge of its starting conditions and composition. Before these observations, scientists thought that all forms of matter and energy in the universe would only cause the expansion to slow down over time.
Ultimate fate of the universeThe ultimate fate of the universe is a topic in physical cosmology, whose theoretical restrictions allow possible scenarios for the evolution and ultimate fate of the universe to be described and evaluated. Based on available observational evidence, deciding the fate and evolution of the universe has become a valid cosmological question, being beyond the mostly untestable constraints of mythological or theological beliefs.
Tired lightTired light is a class of hypothetical redshift mechanisms that was proposed as an alternative explanation for the redshift-distance relationship. These models have been proposed as alternatives to the models that involve the expansion of the universe. The concept was first proposed in 1929 by Fritz Zwicky, who suggested that if photons lost energy over time through collisions with other particles in a regular way, the more distant objects would appear redder than more nearby ones.
Hubble Space TelescopeThe Hubble Space Telescope (often referred to as HST or Hubble) is a space telescope that was launched into low Earth orbit in 1990 and remains in operation. It was not the first space telescope, but it is one of the largest and most versatile, renowned both as a vital research tool and as a public relations boon for astronomy. The Hubble telescope is named after astronomer Edwin Hubble and is one of NASA's Great Observatories.
