Expanding the Polymer Mechanochemistry Toolbox through Surface-Initiated Polymerization
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The development of innovative bioanalytical technologies that enable the discovery of new therapeutics or the creation of systems for rapid, accurate and parallel analyses has gained an extraordinary interest in the biomedical sector in the last 10-15 year ...
Surface-initiated polymerization represents a versatile strategy to modify a diverse range of materials with thin, functional polymer coatings. While in many cases the desired functional groups can be directly incorporated via (co)polymerization of the app ...
Magnetite nanoparticles are synthesized by thermal decomposition of Fe(acac)(3) and subsequently coated with a silica shell exploiting a water-in-oil synthetic procedure. The as-produced nanopowder is mixed with a photocurable hyperbranched resin and the p ...
In this Article, we studied the surface immobilization of five organic-acid-modified atom-transfer radical polymerization (ATRP) initiators based on salicylic acid, catechol, phthalic acid, and m- and p-benzoic add on alumina, and we also investigated the ...
Water-dispersible, polymer-wrapped nanocrystals are highly sought after for use in biol. and chem., from nanomedicine to catalysis. The hydrophobicity of their native ligand shell, however, is a significant barrier to their aq. transfer as single particles ...
While the bulk structure of a material determines its mechanical properties, its surface plays a key role when interactions with the environment are important. Nowadays materials in bio- and nanotechnology are required to possess very complex functionaliti ...
During the past decades the field of sensors has been subject to much attention due to an increased demand for (bio)sensors and environmental monitoring. The efforts have been concentrated to create sensors which are reliable, highly sensitive and selectiv ...
A high penetration grade bitumen has been blended with up to 50 wt% of two different grades of metallocene catalyzed linear low density polyethylene (m-LLDPE) in order to investigate the potential of these and similar copolymers as a substitute for styrene ...
Hydrophilic polymer brushes grown via surface-initiated ATRP from silicon oxide surfaces are susceptible to detachment via hydrolytic cleavage of the anchoring siloxane bond. This paper investigates the influence of the structure of the ATRP initiator on t ...
Virus filtration by size exclusion is a robust means of eliminating viruses in blood or pharma products. Porous polymer membranes with a narrow size distribution are used to allow passage of the protein product but retain viruses. The chosen polymer must r ...