Quantitative feasibility study of magnetocaloric energy conversion utilizing industrial waste heat

The main objective of this theoretical study was to investigate under which conditions a magnetic energy conversion device (MECD) - utilizing industrial waste heat - is economically feasible. Furthermore, it was evaluated if magnetic energy conversion (MCE) has the potential of being a serious concurrent to already existing conventional energy conversion technologies. Up-today the availability of magnetocaloric materials with a high Curie temperature and a high magnetocaloric effect is rather limited. Therefore, this study was mainly focused on applications with heat sources of low to medium temperature levels. Magnetic energy conversion machines, containing permanent magnets, are numerically investigated for operation conditions with different temperature levels, defined by industrial waste heat sources and environmental heat sinks, different magnetic field intensities and different frequencies of operation (number of thermodynamic cycles per unit of time). Theoretical modeling and numerical simulations were performed in order to determine thermodynamic efficiencies and the exergy efficiencies as function of different operation conditions. From extracted data of our numerical results, approximate values of the total mass and total volume of magnetic energy conversion machines could be determined. These important results are presented dependent on the produced electric power. An economic feasibility study supplements the scientific study. It shows an excellent potential of profitability for certain machines. The most important result of this article is that the magnetic energy conversion technology can be economically and technically competitive to or even beat conventional energy conversion technologies. This is true especially in those cases when large, low-exergy heat sources are at one's disposal. (C) 2012 Elsevier Ltd. All rights reserved.

Key Energy and Technological Aspects of Three Innovative Concepts of District Energy Networks

Patrick Chatelan, Daniel Favrat, Samuel Henchoz, François Maréchal

Energy needs in urban areas are heterogeneous by their nature, spatial distribution and temperature level required. Three concepts of district energy networks that could provide the energy services efficiently to a city centre are compared. The focus is on the energy and technological aspects. These networks are characterized by similar temperature levels; between 9.5 °C and 18 °C, rely on free cooling for most of the cooling services and use a combination of centralized and decentralized heat pumps to provide the heating services. Two of these concepts exploit the latent heat of evaporation/condensation of CO2 and of the refrigerant R1234yf to store and transfer heat. The third concept is more conventional and uses the sensible heat of liquid water, however with a small temperature spread. The proposed networks allow the waste heat emitted by the users requiring cooling to be transferred and valourised by the users requiring heating, thus reducing the load on the central plant. For the area considered, where the annual heating and cooling demand are 53.1 GWh and 49.4 GWh respectively, the annual electricity required to supply the thermal services amounts to 10.87 GWh for CO2, 10.52 GWh for water and 9.60 GWh for R1234yf. © 2016 Elsevier Ltd. All rights reserved.

2016

Copper battery for heat to power conversion and energy storage

Sunny Isaïe Maye

An important part of the electricity production relies on heat conversion. Indeed power plants burn fuels like natural gas, coal or use nuclear fission to produce heat that can be transformed into electricity through a thermodynamic cycle and the mechanical work of a turbine. However, with such methods, high efficiencies are only reached with high temperatures according to the Carnot theory. Large amounts of waste heat or low-temperature heat are not converted into electrical power during these processes and are usually simply not exploited. Therefore, there is an opportunity to improve the way in which the heat is used and especially for electricity production, if waste heat can be recovered. Low-grade heat (below 200 â) is available in vast quantities from industry, but also from renewable sources such as solar thermal or geothermal energy. As renewable energies are often available intermittently during specific time of the day or according to the season, the storage of the low-temperature heat coming from these sources is particularly interesting for a more efficient distribution and consumption. However, production of electric power from these heat sources is challenging with existing technologies. Thermally regenerative batteries allow both the conversion and the storage of thermal energy into electric power, but they suffer from low operation voltages and low output powers. Here, we propose a thermally regenerative flow battery based on copper complexation with acetonitrile in non-aqueous solutions operating at voltages above 1V. Cu(I) complex can be destabilized by removal of acetonitrile by distillation, leading to production of solid copper and Cu(II) in a solution of propylene carbonate, thereby charging the battery. With this reaction, we demonstrate the electricity production at power densities up to 200 WÂ·mâ2, and estimate the theoretical efficiency of the full system between 5-14%. The results demonstrate a proof-of-concept for producing and storing electricity from low-quality heat.

EPFL2020

Part load flow in radial centrifugal pumps

Olivier Braun

Centrifugal pumps are required to sustain a stable operation of the system they support under all operating conditions. Minor modifications of the surfaces defining the pump's water passage can influence the tendency to unstable system operation significantly. The action of such modifications on the flow are yet not fully understood, leading to costly trial and error approaches in the solution of instability problems. The part-load flow in centrifugal pumps is inherently time-dependent due to the interaction of the rotating impeller with the stationary diffuser (Rotor-Stator Interaction, RSI). Furthermore, adverse pressure gradients in the pump diffuser may cause flow separation, potentially inducing symmetry-breaking non-uniformities, either spatially stationary or rotating and either steady or intermittent. Rotating stall, characterized by the presence of distinct cells of flow separation on the circumference, rotating at a fraction of the impeller revolution rate, has been observed in thermal and hydraulic turbomachines. Due to its complexity, the part-load flow in radial centrifugal pumps is a major challenge for numerical flow simulation methods. The present study investigates the part-load flow in radial centrifugal pumps and pump-turbines by experimental and numerical methods, the latter using a finite volume discretization of the Reynolds-averaged Navier-Stokes (RANS) equation. Physical phenomena of part load flow are evidenced based on three case studies, and the ability of numerical simulation methods to reproduce part-load flow in radial centrifugal pumps qualitatively and quantitatively is assessed. A numerical study of the flow in a high specific speed radial pump-turbine using steady approaches and the hypothesis of angular periodicity between neighboring blade channels evidences the relation of sudden flow topology changes with an increase of viscous losses, impacting on the energy-discharge characteristic, and thus increasing the risk of unstable operation. When the flow rate drops below a critical threshold, the straight through-flow with flow separation zones attached to the guide vanes changes to an asymmetrical flow. Energy is drawn off the mean flow and dissipated in a large vortex-like structure. Besides flow separation in some diffuser channels, time-dependent numerical simulations of the flow in a double suction pump evidence a flow rate imbalance between both impeller sides interacting with asymmetric flow separation in the diffuser. Viscous losses increase substantially as this imbalance occurs, the resulting segment of positive slope in the energy-discharge characteristic is found for a flow rate sensibly different from measurements. Different modes of rotating stall are identified by transient pressure measurements in a low-specific-speed pump-turbine, showing 3 to 5 zones of separated flow, rotating at 0.016 to 0.028 times impeller rotation rate, depending on discharge. For operating conditions where stall with 4 cells is most pronounced, velocity is measured by Laser-Doppler methods at locations of interest. The velocity field is reconstructed with respect to the passage of stall cells by definition of a stall phase obtained from simultaneous transient pressure measurements. Time-dependent numerical simulation predicting rotating stall with 4 cells shows velocity fields that are in reasonable agreement with the measured velocity fields, but occurring at a sensibly higher flow rate than found from experiments. In consideration of the quantitative shortcomings of the numerical simulation, a novel modelling approach is proposed: Replacing the costly 3-dimensional simulation of the major part of the impeller channels by a 1-dimensional model allows a significant economy in computational resources, allowing an improved modeling for the remainder of the domain at constant computational cost. The model is validated with the challenging cases of rotating stall and impeller side flow rate imbalance. The satisfying coherence of the results with the simulation including the entire impeller channels qualifies this approach for numerous turbomachinery applications. It could also provide improved, time-dependent boundary conditions for draft tube vortex rope simulations at reasonable computational cost. Parameter studies modifying deliberately some quantities of mean flow and turbulence at the modeled boundary surfaces can be implemented in the framework of the method.