Experimental and first-principles study of point defects, domain walls, and point-defect/domain-wall interactions in ferroelectric oxides
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This thesis consists of a theoretical analysis of charged domain walls in ferroelectrics based on Landau theory and the theory of semiconductors. First, the internal structure of a 180-degree charged domain wall is considered. It is shown that different re ...
Orthorhombic Lead metaniobate (PbNb2O6) exhibits ferroelectric properties and has a Curie temperature, TC of 570 degrees C. This work reports on investigations made on ferroelectric Lead metaniobate, (PN) and its solid solutions with bismuth and titanium P ...
We have studied the polarization-electric-field hysteresis, the dielectric permittivity dispersion, the piezoelectric properties, the electric-field-induced strain, and the interrelations between these properties for bismuth ferrite (BiFeO3) ceramics. The ...
Ferroelectric perovskites exhibit superior dielectric, piezoelectric and ferroelectric properties. Architecting ferroelectrics in the small scale holds interest in both application and fundamental research. Compared to their 2D counterparts – thin films, f ...
The manner in which 90. ferroelectric-ferroelastic domains respond to changes in temperature has been mapped in BaTiO3 single crystals using atomic force microscopy. Domain periodicity remains unaltered until approximately 2 degrees C below the Curie tempe ...
Lead zirconate titanate (Pb(Zr1-xTix)O3 or PZT) ferroelectric ceramics have been widely used in transducers, actuators, and sensors, since they posses high dielectric and piezoelectric properties with a relatively high temperature of operation. Commerciall ...
We report on the frequency and stress dependence of the direct piezoelectric d33 coefficient in BiFeO3 ceramics. The measurements reveal considerable piezoelectric nonlinearity, i.e., dependence of d33 on the amplitude of the dynamic stress. The nonlinear ...
P-type AlInN layers lattice-matched to GaN are achieved by Mg doping. The net acceptor concentration N-A-N-D is 5 x 10(18) cm(-3) at a Mg concentration [Mg] of similar to 2 x 10(19) cm(-3). Mg acceptors are partly compensated and one of the compensating de ...
The influence of flexoelectric coupling on the internal structure of neutral domain walls in the tetragonal phase of perovskite ferroelectrics is studied. The effect is shown to lower the symmetry of 180 degrees walls which are oblique with respect to the ...
The position of (Fe-Zr',(Ti)-V-O(center dot center dot))(center dot) defect complexes in Pb[Zr0.52Ti0.48]O-3 (PZT) piezoelectric ceramics was investigated by means of electron paramagnetic resonance (EPR) spectroscopy. The method of analysis pursued to obt ...