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2-(Trifluoromethyl)indoles via Pd(0)-Catalyzed C(sp(3))-H Functionalization of Trifluoroacetimidoyl Chlorides

Related publications (35)

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Citizen Bench. Seating needs and Preferences

Renate Albrecher

The project "Citizen Bench" aimed a better understanding of the variety of urban seating-needs. This report summarises the results of the citizen engagement project on public benches in the City of Munich. In the framework of this pilot project, a method ...

EPFL2022

Streamlined Alkylation via Nickel-Hydride-Catalyzed Hydrocarbonation of Alkenes

Xile Hu, Chao Fan, Srikrishna Bera, Zhikun Zhang

Compounds rich in sp(3)-hybridized carbons are desirable in drug discovery. Nickel-catalyzed hydrocarbonation of alkenes is a potentially efficient method to synthesize these compounds. By using abundant, readily available, and stable alkenes as pro-nucleo ...

AMER CHEMICAL SOC2022

Learning the Exciton Properties of Azo-dyes

Ksenia Briling, Alberto Fabrizio, Sergio Vela Llausi

The ab initio determination of electronic excited state (ES) properties is the cornerstone of theoretical photochemistry. Yet, traditional ES methods become impractical when applied to fairly large molecules, or when used on thousands of systems. Machine l ...

AMER CHEMICAL SOC2021

The Seminar is addressed to doctoral students in the fields of Architecture, Urbanism, Global Health & Humanities and Social Sciences, interested in the use of the One Health concept (OH) as a tool to tackle urban themes (the city, the territory and the wa ...

2021

Carboxylic acids are one of the most suitable starting materials for synthesis. They are readily available and therefore inexpensive, stable and non-toxic. Many carboxylic acids can be obtained directly from natural resources, thus avoiding the extraction ...

EPFL2020

The dilemma between acid and base catalysis in the synthesis of benzimidazole from o-phenylenediamine and carbon dioxide

Paul Joseph Dyson, Simon Nussbaum, Martin Hulla, Alexy Robert Bonnin

The tandem synthesis of benzimidazole and other azoles can be achived by the N-formylation of ortho-substituted anilines followed by a cyclization reaction. However, CO2-based N-formylations with hydrosilane reducing agents are base catalyzed whereas the c ...

2019

Practical and Scalable Synthesis of 7-Azetidin-1-yl-4-(hydroxymethyl)coumarin: An Improved Photoremovable Group

Pablo Rivera Fuentes

A robust and scalable route to prep. the 7-azetidinylated alc., a useful precursor for the photoprotection of a variety of leaving groups, and its use in the prepn. of model phosphate, sulfonate, and carbamate derivs. is presented. ...

2018

Arithmetic and geometric structures in cryptography

Benjamin Pierre Charles Wesolowski

We explore a few algebraic and geometric structures, through certain questions posed by modern cryptography. We focus on the cases of discrete logarithms in finite fields of small characteristic, the structure of isogeny graphs of ordinary abelian varietie ...

EPFL2018

CARTHA / The Form of Form / Issue I / How to Learn Better

Dieter Dietz, Daniel Zamarbide Elizondo

CARTHA is a curated platform that focuses on sharing different forms of critical thinking regarding architecture and society. Through opinions, experiences and works, CARTHA aims to map out the contemporary architectural landscape. How to Learn Better inau ...

2016

A magnetic tunnel to shelter hyperpolarized fluids

Geoffrey Bodenhausen, Aurélien Bornet, Pascal Miéville, Roger Mottier, Sami Jannin, Jonas Milani, Basile Vuichoud

To shield solutions carrying hyperpolarized nuclear magnetization from rapid relaxation during transfer through low fields, the transfer duct can be threaded through an array of permanent magnets. The advantages are illustrated for solutions containing hyp ...

American Institute of Physics2015