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Molecularly Engineered Ru(II) Sensitizers Compatible with Cobalt(II/III) Redox Mediators for Dye-Sensitized Solar Cells

Related publications (32)

Electron-Selective Layers for Dye-Sensitized Solar Cells Based on TiO2 and SnO2

Michael Graetzel, Shaik Mohammed Zakeeruddin, Ladislav Kavan

Titanium dioxide (anatase, rutile) and quasi-amorphous tin dioxide are prepared on F-doped SnO2 in the form of dense thin films, which can serve as electron-selective layers in perovskite solar cells and dye-sensitized solar cells (DSSCs). The present stud ...

2020

An Unsymmetrical, Push-Pull Porphyrazine for Dye-Sensitized Solar Cells

Michael Graetzel, Mohammad Khaja Nazeeruddin

An unsymmetrical, push-pull porphyrazine derivative bearing an isoindole-4-carboxylic acid moiety (TT112) is synthesized and incorporated in a dye-sensitized solar cell (DSSC). The device, which constitutes the first example of a porphyrazine-sensitized so ...

Wiley-V C H Verlag Gmbh2017

Influence of Ionic Liquid Electrolytes on the Photovoltaic Performance of Dye-Sensitized Solar Cells

Shaik Mohammed Zakeeruddin, Jean-David Décoppet

New binary ionic liquid electrolytes based on 1-methyl-1-butylpyrrolidinium bis(trifluromethylsulfonyl)imide, 1-butylpyridinium bis(trifluromethylsulfonyl)imide, 1-methyl-3-ethylimidazolium bis(trifluromethylsulfonyl)imide, 1-methyl-3-ethylimidazolium tetr ...

Wiley-V C H Verlag Gmbh2017

Influence of Ancillary Ligands in Dye-Sensitized Solar Cells

Michael Graetzel, Mohammad Khaja Nazeeruddin

A review. Dye-sensitized solar cells (DSSCs) have motivated many researchers to develop various sensitizers with tailored properties involving anchoring and ancillary ligands. Ancillary ligands carry favorable light-harvesting abilities and are therefore c ...

Amer Chemical Soc2016

Unraveling the Dual Character of Sulfur Atoms on Sensitizers in Dye-Sensitized Solar Cells

Mohammad Khaja Nazeeruddin, Jacques-Edouard Moser, Peng Gao, Thomas Moehl, Joël Teuscher, Aswani Yella, Sadig Aghazada

Cyclometalated ruthenium sensitizers have been synthesized that differ with number of thiophene units on the auxiliary ligands. Sensitizers possessing four (SA25, SA246, and SA285) or none (SA282) sulfur atoms in their structures, were tested in solar cell ...

Amer Chemical Soc2016

3,4-Ethylenedioxythiophene-based cobalt complex: An efficient co-mediator in dye-sensitized solar cells with poly(3,4-ethylenedioxythiophene) counter-electrode

Nikolaos Vlachopoulos, Ulf Anders Hagfeldt, Kazuteru Nonomura, Enrico Polanski

© 2015 Elsevier Ltd. All rights reserved. A mixture of Co(phen)3+/2+ and Co(EtPy)3+/2+ complexes, where EtPy is a terpyridine ligand bearing an 3,4- ethylenedioxythiophene (EDOT) substituent, has been used as redox mediator in dye-sensitized solar cells. T ...

Pergamon-Elsevier Science Ltd2015

Molecular gelation of ionic liquid-sulfolane mixtures, a solid electrolyte for high performance dye-sensitized solar cells

Michael Graetzel, Shaik Mohammed Zakeeruddin, Jean-David Décoppet, Thomas Moehl

Cyclohexanecarboxylic acid-[4-(3-tetradecylureido)phenyl]amide is an efficient gelator to solidify ionic liquid electrolytes. In this paper we apply this low molecular weight gelator to solidify the newly prepared sulfolane based ionic liquid electrolyte. ...

Royal Society of Chemistry2014

Panchromatic symmetrical squaraines: a step forward in the molecular engineering of low cost blue-greenish sensitizers for dye-sensitized solar cells

Michael Graetzel, Mohammad Khaja Nazeeruddin, Jun Ho Yum, Davide Di Censo, Elisa Dell'Orto, Guido Viscardi

Two novel symmetrical blue squaraine sensitizers were synthesized, which exhibit panchromatic light harvesting and a record efficiency over 6% with J(sc) exceeding 14 mA cm(-2), and V-oc over 620 mV under 1 sun. Their color, low cost, easiness of synthesis ...

Royal Soc Chemistry2014

Highly Stable Dye-Sensitized Solar Cells Based on Novel 1,2,3-Triazolium Ionic Liquids

Michael Graetzel, Paul Joseph Dyson, Shaik Mohammed Zakeeruddin, Hoi Nok Tsao

We describe the design and synthesis of novel low viscosity bicyclic 1,2,3-triazolium ionic liquids. These new salts are applied as nonvolatile electrolytes in dye-sensitized solar cells, affording efficiencies up to 7.07% at low light intensities, and 6.0 ...

Amer Chemical Soc2014

Thermal stability of the DSC ruthenium dye C106 in robust electrolytes

Michael Graetzel, Shaik Mohammed Zakeeruddin, Péter Kalman Péchy

We have investigated the thermal stability of the heteroleptic ruthenium complex C106 employed as a sensitizer in dye-sensitized solar cells. The C106 was adsorbed on TiO2 particles and exposed to 2 different iodide/triidode based redox electrolytes A and ...

Pergamon-Elsevier Science Ltd2014

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