Synthesis and Phase Stability of Metastable Bixbyite V2O3 Colloidal Nanocrystals
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One-dimensional microrods (4-5 mm) of PbI2 and CH3NH3PbI3 (MAPbI(3)) with unique structural and morphological properties have been grown at room temperature. X-ray diffraction (XRD) patterns of both types of micro-rods exhibit a hexagonal system (P3m1(164) ...
Supported ruthenium was used in the liquid phase catalytic transfer hydrogenation of furfural. To improve the stability of Ru against leaching, phosphorous was introduced on a Ru/Al2O3 based catalyst upon impregnation with ammonium hypophosphite followed b ...
In this work, we have studied various aspects of catalysts and catalytic processes at the solid-liquid interface, e.g. the reduction of supported PdO, the formation of Pd hydrides, their quantification, the their reactivity in a transient in time-resolved ...
In the present study the transformation between Cu2SnS3, Cu3SnS4 and Cu4SnS4 compounds is analyzed by means of X-ray diffraction and Raman scattering spectroscopy. A detailed analysis of the X-ray diffractograms showed the dependence of formation of the in ...
Four new Schiff-bases have been synthesized from the 1:2 M condensation of 4,5,6,7-tetrahydrobenzothiazole-2,6-diamine with 2-hydroxybenzaldehyde (SL3), 5-Bromo-2-hydroxybenzaldehyde (SL2), 2-hydroxy-3-methoxybenzaldehyde (SL3) and 2-hydroxy-1-naphthaldehy ...
The bidentate carboxamide ligand N-(thiazole-2-yl) picolinamide (LH) was synthesized in the environmentally friendly ionic liquid TBAB, and the five-coordinated Cu-II-complex, [Cu(L)(2)(H2O)]center dot CHCl3 (1) was synthesized from LH and copper(II)acetat ...
During the last decade, III-VI layered semiconductors (GaSe, InSe, GaS, etc.) have emerged as potential candidates for various applications, such as FET and optoelectronic devices. The properties of this class of layered materials are strongly dependent on ...
The zein solutions containing different concentrations of cuminaldehyde (5%, 10%, and 20%, w/w) were electrospun. The morphology and average diameter of fibers were evaluated by scanning electron microscopy and the optimized fiber (20% cuminaldehyde) was c ...
The chemistry of divalent lanthanides has generated increasing interest in the past years due to their redox properties and unique reaction pathways. Notably, molecular complexes of low-valent lanthanides have been shown to be suitable one-electron reducta ...
Solving native structures of such large molecules, like biomolecules, is often challenging, particularly due to the potentially infinite number of non-covalent interactions with water. In this thesis, we report the use of cold ion gas-phase action spectros ...