Experimental and theoretical studies on electropolymerization of polar amino acids on platinum electrode
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The invention describes a method for electrochem. producing the peroxodisulfuric acid and peroxodisulfates by electrochem. oxidn. of sulfuric acid. The process was carried using on an anode which, preferably, was not completely prepolarized and which was c ...
(Fraunhofer-Gesellschaft zur Foerderung der Angewandten Forschung E.V., Germany; CSEM Centre Suisse d'Electronique et de Microtechnique S.A.).2001
The invention provides a device for obtaining an improved efficiency in a photovoltaic, nanostructured, dye sensitized cell structure, comprising a photoactive working electrode, a counter electrode and an electrolyte arranged there-between. The cell struc ...
A newly designed thin-layer STM (TLSTM) technique is presented based on a microfabricated probe combining an electrolytic STM probe with an annular iridium oxide microelectrode operating as a potential-controlled generator or scavenger of H+. This TLSTM co ...
Synthetic boron-doped diamond (BDD) thin film electrodes were tested for the electrogeneration of silver(II). In nitric acid, the kinetics of the silver(I)/silver(II) couple were studied by cyclic voltammetry. The results demonstrate that silver(II) can be ...
A thin aqueous layer is formed between the polymeric ion-selective membrane and an inner gold electrode. Its composition can be altered upon sample changes, which leads to drifting potentials. It is shown by theory and experiment that interfering ions ente ...
Secondary fly ash, resulting from thermal treatment processes, leads to a highly concd. chloride soln. with Cu, Pb, Cd and Zn as main heavy metals when dissolved in water. The selective electrodeposition of these heavy metals was studied. The goal was to r ...
Polyethylene block-copolymer films containing negative anhydride groups were used to immobilize TiO2, Fe2O3, and Fe3+ photocatalysts. The kinetics of the mineralization of azo-dye Orange II and chlorophenols on copolymer−TiO2, copolymer−Fe2O3, and copolyme ...
Nanocrystalline electrochromic electrodes offer a promising outlook for the realization of displays characterized by sharp contrast and fast switching. These electrodes are constituted of sintered nanoparticles of a semiconductor, for instance titanium dio ...
Linear peptide H-Pro-Thr(Psi(Me,Me)pro)-Pro-OH containing a preformed cis-Pro-Thr(Psi(Me,Me)pro) tertiary amide bond cyclises instantaneously and free of formation of oligomeric structures to the cyclic tripeptide cyclo-[Pro-Thr(Psi(Me,Me)pro)-Pro]. Even a ...
A novel electrochemiluminescence (ECL) detector is presented in this article. The detector is applied for micellar electrokinetic chromatographic separation of dichlorotris(2,2′-bipyridyl)ruthenium(II) hydrate [Ru(bpy)] and dichlorotris(1,10-phenanthroline ...