Formic Acid as a Hydrogen Carrier for Fuel Cells Toward a Sustainable Energy System
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Bromide promoted decompn. of tert-Bu bromide in the presence of triphenylphosphine gives, besides isobutene, hydrogen(triphenyl)phosphonium bromide. When heated to approx. 150 DegC in the presence of xylene, the latter salt liberates hydrogen bromide which ...
A review with 62 refs. The appropriate choice of a metalating reagent is the key to the optional deprotonation of benzylamine derivs. at a position adjacent to the substituent or the nitrogen bearing side chain or even at the benzylic a-position of the lat ...
Methanol dehydrogenation to formaldehyde was conducted in a fixed-bed flow reactor with sodium carbonate catalyst mixed with active carbons or transition metals. The additives promoted the reaction rate at 880-970 K without modifying formaldehyde selectivi ...
The advantage of coupling a diffuse-reflectance infrared cell with a continuous-feed recycle reactor for in situ kinetic and mechanistic studies is illustrated in the study of CO2 methanation over Ru/TiO2. From transient and steady-state experiments, metal ...
The photodissociation of water into hydrogen gas is mediated by a catalytic dispersion of fine metal particles. This dispersion is stabilized by polymers of alkylene glycols which are adsorptive to said particles and which act as protective agents in solut ...
Ion-bombarded polystyrene with a 0.5-keV Ar+ beam has been investigated by means of photoelectron spectroscopy performed with synchrotron radiation. After a dose of 10(15) ions/cm2 the evolution of the valence band of the bombarded sample towards an amorph ...
Particle tagging in a tokamak provides an attractive method for studying transport mechanisms. The injection of test particles at the plasma edge and the subsequent measurement of the evolution of their concentration at the centre can be used to quantify t ...
The effects of hydrogen diffusion on p-n GaAs junctions have been studied by electron beam induced current (EBIC) and cathodoluminescence (CL) at room temperature. Hydrogen passivates both the acceptors in the p-side of the junction and the donors in the n ...
Sodium salts such as Na2CO3 and Na molybdate are active and selective MeOH dehydrogenation catalysts for the prodn. of water-free HCHO. Profound chem. and structural changes are experienced by the molybdate when employed under normal reaction conditions (5 ...