Predicting Product Distribution of Propene Dimerization in Nanoporous Materials
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Deprotonation-triggered heavy halogen migrations should become a favorite tool in arene synthesis if their occurrence and outcome could be made predictable. Particularly attractive, though extremely rare, are stop-and-go situations where a first intermedia ...
Me groups adjacent to an olefinic double bond were metalated by KOCMe3 and BuLi without cis-trans isomerization. Thus, (E)-MeCH:-CHMe was metalated to give (E)-MeCH:CHCH2K (I) which reacted with ethylene oxide to give 41% (E)-MeCH:CH(CH2)3OH. If I was allo ...
The reactions of the cluster complexes [Pt-3(mu -Co)(3)L-3], where L = PPh3 1a, PPh(2)Bz 1b and PCy3 1c, with activated mono-olefins have been studied under preparative and equilibrium conditions. At low temperature the olefins react quantitatively giving ...
A review of kinetic control in the diastereogenic formation of C-C bonds, Diels-Alder reactions, [2 + 2] cyclodimerization of olefins, syn preference in the formation of cyclopropanes from olefins and monosubstituted carbenes, reactions of organometallics ...
Whereas triphenylphosphonioethanide manifests unsatisfactory cis-selectivities (84.0-95.5%), tris(o,o'-difluorophenyl)- and tri-o-tolylphosphonioethanide react with aliph. or arom. aldehydes and, resp., 2-alkenals or 2-alkynals to afford the olefins with c ...
The soln. structure of the two intimate ion pairs present in soln. for [PtMe(h2-olefin)(a-diimine)]BF4 compds. (1-3, shown as I.BF4, R = Ph, 4-MeC6H4, 4-CF3C6H4) their relative abundance and the consequent thermodn. equil. parameters were detd. by a quant. ...
Merits and drawbacks of known C-C linking procedures, such as condensation, addn., and isomerization reactions, are outlined. Two novel methods are discussed in more detail: the Cu-catalyzed alkylation of Grignard reagents, and reactions with allylpotassiu ...
Different micellar systems are characterized. Hydroformylation reactions are carried out in the most appropriate ones and are compared with hydroformylations in a non-micellar system. Reaction rates and selectivities for aldehydes are higher than the micel ...
Merits and drawbacks of known C-C linking procedures, such as condensation, addn., and isomerization reactions, are outlined. Two novel methods are discussed in more detail: the Cu-catalyzed alkylation of Grignard reagents, and reactions with allylpotassiu ...
