Development of heterogeneous catalytic systems for the transformation of carbon dioxide to methanol under mild conditions.
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Actually the world is facing the dual challenge of energy supply security and mitigating climate change due to greenhouse gas emissions. In this context different alternatives to reduce the atmospheric CO2 emissions are increasing the efficiency, switching ...
The reactivity of five di-n-butyltin(IV) complexes, n-Bu2Sn(OR)(2) (1), n-Bu2SnO (3), n-Bu2Sn(OR)O (4), (n-Bu2SnO)(2)(CO2) (6) and (n-Bu2SnO)(6)(n-Bu2SnOR)(2)(CO3) (7) (R = CH3), with CO2, suggested as possible catalyst precursors and key-interme ...
Within the global challenge of climate change and energy security, hydrogen is considered as a promising decarbonized energy vector to be used in electricity production and transportation. In this paper, the thermo-chemical production of hydrogen by natura ...
A simple and straightforward method has been developed for the direct carboxylation of aromatic heterocylces such as oxazoles, thiazoles, and oxadiazoles using CO2 as the C1 source. The reactions require no metal catalyst and only Cs2CO3 as the base. A goo ...
Hydrogen is one of the essential reactants in the chemical industry, though its generation from renewable sources and storage in a safe and reversible manner remain challenging. Formic acid (HCO2H or FA) is a promising source and storage material in this r ...
The mechanism of reaction between NO and two models of carbonaceous materials with active sites was investigated at the UB3LYP/6-31 + G(d) and UM06-2X theory levels. The small model is the anthracene radical and the large one is also a monoradical built wi ...
Among the different ways of capturing carbon dioxide in industrial processes, chemical looping process is presented as an improvement in oxy-fuel combustion. Since carbon dioxide is directly generated with water in the process, there is no need of an addit ...
We apply an evolutionary game theoretic approach to the evolution of dispersal in explicitly spatial metacommunities, using a flexible parametric class of dispersal kernels, namely 2Dt kernels, and study the resulting evolutionary dynamics and outcomes. We ...
There has been growing concern about the way cultivating biomass for the production of agro-biofuels competes with food production. To avoid this competition biomass production for biofuels will, in the long term, have to be completely decoupled from food ...
Centred on research and development in Solar Energy Applications to the Built Environment, the International Conference CISBAT 2007, organised every other year on the campus of the Swiss Federal Institute of Technology (EPFL) in Lausanne/Switzerland, once ...