Entropy of activationIn chemical kinetics, the entropy of activation of a reaction is one of the two parameters (along with the enthalpy of activation) which are typically obtained from the temperature dependence of a reaction rate constant, when these data are analyzed using the Eyring equation of the transition state theory. The standard entropy of activation is symbolized ΔS‡ and equals the change in entropy when the reactants change from their initial state to the activated complex or transition state (Δ = change, S = entropy, ‡ = activation).
Reaction rateThe reaction rate or rate of reaction is the speed at which a chemical reaction takes place, defined as proportional to the increase in the concentration of a product per unit time and to the decrease in the concentration of a reactant per unit time. Reaction rates can vary dramatically. For example, the oxidative rusting of iron under Earth's atmosphere is a slow reaction that can take many years, but the combustion of cellulose in a fire is a reaction that takes place in fractions of a second.
High-pressure areaA high-pressure area, high, or anticyclone, is an area near the surface of a planet where the atmospheric pressure is greater than the pressure in the surrounding regions. Highs are middle-scale meteorological features that result from interplays between the relatively larger-scale dynamics of an entire planet's atmospheric circulation. The strongest high-pressure areas result from masses of cold air which spread out from polar regions into cool neighboring regions. These highs weaken once they extend out over warmer bodies of water.
CloudIn meteorology, a cloud is an aerosol consisting of a visible mass of miniature liquid droplets, frozen crystals, or other particles suspended in the atmosphere of a planetary body or similar space. Water or various other chemicals may compose the droplets and crystals. On Earth, clouds are formed as a result of saturation of the air when it is cooled to its dew point, or when it gains sufficient moisture (usually in the form of water vapor) from an adjacent source to raise the dew point to the ambient temperature.
Activated complexIn chemistry an activated complex is defined by the International Union of Pure and Applied Chemistry (IUPAC) as "that assembly of atoms which corresponds to an arbitrary infinitesimally small region at or near the col (saddle point) of a potential energy surface". In other words, it refers to a collection of intermediate structures in a chemical reaction that persist while bonds are breaking and new bonds are forming.
Reaction progress kinetic analysisIn chemistry, reaction progress kinetic analysis (RPKA) is a subset of a broad range of kinetic techniques utilized to determine the rate laws of chemical reactions and to aid in elucidation of reaction mechanisms. While the concepts guiding reaction progress kinetic analysis are not new, the process was formalized by Professor Donna Blackmond (currently at Scripps Research Institute) in the late 1990s and has since seen increasingly widespread use.
Norwegian cyclone modelThe older of the models of extratropical cyclone development is known as the Norwegian cyclone model, developed during and shortly after World War I within the Bergen School of Meteorology. In this theory, cyclones develop as they move up and along a frontal boundary, eventually occluding and reaching a barotropically cold environment. It was developed completely from surface-based weather observations, including descriptions of clouds found near frontal boundaries.
Polar lowA polar low is a mesoscale, short-lived atmospheric low pressure system (depression) that is found over the ocean areas poleward of the main polar front in both the Northern and Southern Hemispheres, as well as the Sea of Japan. The systems usually have a horizontal length scale of less than and exist for no more than a couple of days. They are part of the larger class of mesoscale weather systems. Polar lows can be difficult to detect using conventional weather reports and are a hazard to high-latitude operations, such as shipping and gas and oil platforms.
AerosolAn aerosol is a suspension of fine solid particles or liquid droplets in air or another gas. Aerosols can be natural or anthropogenic. Examples of natural aerosols are fog or mist, dust, forest exudates, and geyser steam. Examples of anthropogenic aerosols include particulate air pollutants, mist from the discharge at hydroelectric dams, irrigation mist, perfume from atomizers, smoke, dust, steam from a kettle, sprayed pesticides, and medical treatments for respiratory illnesses.
Transition state theoryIn chemistry, transition state theory (TST) explains the reaction rates of elementary chemical reactions. The theory assumes a special type of chemical equilibrium (quasi-equilibrium) between reactants and activated transition state complexes. TST is used primarily to understand qualitatively how chemical reactions take place.
