Liquid crystalLiquid crystal (LC) is a state of matter whose properties are between those of conventional liquids and those of solid crystals. For example, a liquid crystal may flow like a liquid, but its molecules may be oriented in a crystal-like way. There are many types of LC phases, which can be distinguished by their optical properties (such as textures). The contrasting textures arise due to molecules within one area of material ("domain") being oriented in the same direction but different areas having different orientations.
Joule expansionThe Joule expansion (also called free expansion) is an irreversible process in thermodynamics in which a volume of gas is kept in one side of a thermally isolated container (via a small partition), with the other side of the container being evacuated. The partition between the two parts of the container is then opened, and the gas fills the whole container. The Joule expansion, treated as a thought experiment involving ideal gases, is a useful exercise in classical thermodynamics.
Air-free techniqueAir-free techniques refer to a range of manipulations in the chemistry laboratory for the handling of compounds that are air-sensitive. These techniques prevent the compounds from reacting with components of air, usually water and oxygen; less commonly carbon dioxide and nitrogen. A common theme among these techniques is the use of a fine (100–10−3 Torr) or high (10−3–10−6 Torr) vacuum to remove air, and the use of an inert gas: preferably argon, but often nitrogen.
Air sensitivityAir sensitivity is a term used, particularly in chemistry, to denote the reactivity of chemical compounds with some constituent of air. Most often, reactions occur with atmospheric oxygen (O2) or water vapor (H2O), although reactions with the other constituents of air such as carbon monoxide (CO), carbon dioxide (CO2), and nitrogen (N2) are also possible. A variety of air-free techniques have been developed to handle air-sensitive compounds. Two main types of equipment are gloveboxes and Schlenk lines.
Michael AtiyahSir Michael Francis Atiyah (əˈtiːə; 22 April 1929 – 11 January 2019) was a British-Lebanese mathematician specialising in geometry. His contributions include the Atiyah–Singer index theorem and co-founding topological K-theory. He was awarded the Fields Medal in 1966 and the Abel Prize in 2004. Atiyah was born on 22 April 1929 in Hampstead, London, England, the son of Jean (née Levens) and Edward Atiyah. His mother was Scottish and his father was a Lebanese Orthodox Christian.
James Prescott JouleJames Prescott Joule (dʒuːl; 24 December 1818 - 11 October 1889) was an English physicist, mathematician and brewer, born in Salford, Lancashire. Joule studied the nature of heat, and discovered its relationship to mechanical work. This led to the law of conservation of energy, which in turn led to the development of the first law of thermodynamics. The SI derived unit of energy, the joule, is named after him. He worked with Lord Kelvin to develop an absolute thermodynamic temperature scale, which came to be called the Kelvin scale.
