Publications related to Copper-catalyzed remote C(sp3)–H azidation and oxidative trifluoromethylation of benzohydrazides

A Bayesian Bandit Approach to Adaptive Delay-based Congestion Control

Adapting the transmission rate of video telephony Internet applications in order to guarantee the maximal communication quality is still an open and extremely challenging problem. The congestion control algorithm, which is the algorithm responsible for adj ...

ASSOC COMPUTING MACHINERY2018

Base-Free Transfer Hydrogenation with an Ionic-Liquid-Supported Ruthenium eta(6)-Arene Bis(pyrazolyl)methane Catalyst

Paul Joseph Dyson, Francisco Sepulveda, Andrew Douglas Phillips

Ruthenium complexes of the type [RuCl(eta(6)-arene)-(NN)]X (X = BF4 or BPh4) featuring an eta(6)-arene ligand modified with an imidazolium ring and incorporating the bis(azo) chelating (NN) ligands 2-hydroxyphenylbis(3,5-dimethylpyrazol-1-yl) methane or 2- ...

Wiley-Blackwell2017

Synthesis of cyclic carbonates from diols and CO2 catalyzed by carbenes

Paul Joseph Dyson, Felix Daniel Bobbink, Martin Hulla, Shoubhik Das, Weronika Gruszka

The synthesis of cyclic carbonates from epoxides and CO2 is a well-established reaction, whereas the synthesis of cyclic carbonates from diols and CO2 is considerably more challenging, and few efficient catalysts are available. Here, we describe heterocycl ...

2016

On-Surface Assembly and Reactions of Organic Molecules in Ultra-High Vacuum

Claudius Morchutt

This thesis comprises the study of two types of 2D materials, those stabilized by non-covalent and those by covalent interactions. They are synthesized and studied on well-defined metallic surfaces in ultra-high vacuum (UHV). The self-assembly of terephtha ...

EPFL2016

The Molecular Mechanism of the Catalase-like Activity in Horseradish Peroxidase

Ursula Röthlisberger, Pablo Campomanes Ramos

Horseradish peroxidase (HRP) is one of the most relevant peroxidase enzymes, used extensively in immunochemistry and biocatalysis applications. Unlike the closely related catalase enzymes, it exhibits a low activity to disproportionate hydrogen peroxide (H ...

2015

Carbon supported gold and silver: Application in the gas phase hydrogenation of m-dinitrobenzene

Lioubov Kiwi, Fernando Cardenas Lizana

We have studied the gas phase continuous hydrogenation of m-dinitrobenzene (m-DNB) over acid treated activated carbon (AC) supported Au and Ag prepared by deposition-precipitation. Temperature programmed reduction of a 1%wt. metal loading generated a broad ...

Elsevier Science Bv2015

Surface Reactions are Crucial for Energy Storage

Philippe Mauron, Shunsuke Kato, Elsa Callini

Reactions between gas molecules, e.g. H-2 and CO2 and solids take place at the surface. The electronic states and the local geometry of the atomic arrangement determine the energy of the adsorbate, i.e. the initial molecule and the transition state. Here w ...

Schweizerische Chemische Gesellschaft2015

The Next 700 BFT Protocols

Rachid Guerraoui, Marko Vukolic, Nikola Knezevic

Modern Byzantine fault-tolerant state machine replication (BFT) protocols involve about 20,000 lines of challenging C++ code encompassing synchronization, networking and cryptography. They are notoriously difficult to develop, test and prove. We present a ...

2010

Kinetics of the solvent-free hydrogenation of 2-methyl-3-butyn-2-ol over a structured Pd-based catalyst

Albert Renken, Lioubov Kiwi, Rocio Micaela Crespo Quesada, Martin Grasemann

The solvent-free selective hydrogenation of 2-methyl-3-butyn-2-ol (MBY) to 2-methyl-3-buten-2-ol (MBE) was studied over a Pd/ZnO structured catalyst and compared to its behavior in water-assisted conditions. The catalytic behavior was correlated with the s ...

2009

Three-Phase Catalytic Hydrogenation of a Functionalized Alkyne: Mass Transfer and Kinetic Studies with in Situ Hydrogen Monitoring

Albert Renken, Lioubov Kiwi, Martin Grasemann

Systematic studies of mass transfer interactions with intrinsic reaction kinetics were performed for the threephase selective hydrogenation of 2-methyl-3-butyn-2-ol (MBY) to 2-methyl-3-buten-2-ol (MBE) over a modified Pd/CaC

{O}_{3}

catalyst under solvent ...

2008

Copper-catalyzed remote C(sp3)–H azidation and oxidative trifluoromethylation of benzohydrazides

Graph Chatbot

Chat with Graph Search

A Bayesian Bandit Approach to Adaptive Delay-based Congestion Control

Base-Free Transfer Hydrogenation with an Ionic-Liquid-Supported Ruthenium eta(6)-Arene Bis(pyrazolyl)methane Catalyst

Synthesis of cyclic carbonates from diols and CO2 catalyzed by carbenes

On-Surface Assembly and Reactions of Organic Molecules in Ultra-High Vacuum

The Molecular Mechanism of the Catalase-like Activity in Horseradish Peroxidase

Carbon supported gold and silver: Application in the gas phase hydrogenation of m-dinitrobenzene

Surface Reactions are Crucial for Energy Storage

The Next 700 BFT Protocols

Kinetics of the solvent-free hydrogenation of 2-methyl-3-butyn-2-ol over a structured Pd-based catalyst

Three-Phase Catalytic Hydrogenation of a Functionalized Alkyne: Mass Transfer and Kinetic Studies with in Situ Hydrogen Monitoring

Base-Free Transfer Hydrogenation with an Ionic-Liquid-Supported Ruthenium eta(6)-Arene Bis(pyrazolyl)methane Catalyst

On-Surface Assembly and Reactions of Organic Molecules in Ultra-High Vacuum

The Molecular Mechanism of the Catalase-like Activity in Horseradish Peroxidase

The Next 700 BFT Protocols

Surface Reactions are Crucial for Energy Storage

A Bayesian Bandit Approach to Adaptive Delay-based Congestion Control

Three-Phase Catalytic Hydrogenation of a Functionalized Alkyne: Mass Transfer and Kinetic Studies with in Situ Hydrogen Monitoring

Kinetics of the solvent-free hydrogenation of 2-methyl-3-butyn-2-ol over a structured Pd-based catalyst

Synthesis of cyclic carbonates from diols and CO2 catalyzed by carbenes

Carbon supported gold and silver: Application in the gas phase hydrogenation of m-dinitrobenzene