Optimizing Mesostructured Silver Catalysts for Selective Carbon Dioxide Conversion into Fuels
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This thesis investigates the effect of different parameters such as Fe (III), D-gluconate and heterogeneous particles on the nucleation and growth of synthetic C-S-H by using the dropwise precipitation method. Firstly, the effect of Fe (III) on the synthet ...
A better understanding of silica dissolution-precipitation reactions at high pH aqueous solutions allows for promotion of favorable (e.g., pozzolanic) reactions and mitigation of deleterious (e.g., alkali-silica) reactions in concrete. In this paper, the k ...
The Tiermas low temperature geothermal system, hosted in the Paleocene-Eocene carbonates of the Jaca-Pamplona basin, has been studied to evaluate the geochemistry and the temperature of the waters in the deep reservoir. These waters are of chloride-sodium ...
Calcium-containing slag material is produced in iron- and steelmaking worldwide, including Finland. One process route utilizing this calcium, being developed towards large-scale application, is the so-called slag2pcc concept. Using ammonium salts, up to 50 ...
Villigen PSI, World Resources Forum, printed by Paul Scherrer Institute2015
Understanding the structure and dynamics of water's constituent ions, proton and hydroxide, has been a subject of numerous experimental and theoretical studies over the last century. Besides their obvious importance in acid-base chemistry, these ions play ...
The anodic oxidation of polar amino acids (L-serine, L-threonine, L-asparagine, and L-glutamine) in aqueous electrolyte on smooth platinum electrode was carried out by cyclic voltammetry coupled to electrochemical quartz crystal microbalance (EQCM). pH (zw ...
This paper reports on the electrochemical characterization and comparison of printable silver inks for the fabrication of planar electrodes to integrate in a microfluidic platform for in situ desalination of seawater prior to detection of nutrients in mari ...
The electrochemical reduction of CO2 to CO is a reaction of central importance for sustainable energy conversion and storage. Herein, structure activity relationships of a series of imidazolium-based cocatalysts for this reaction are described, which demon ...
Calcium silicate hydrate (C-S-H) is the main hydrate phase in Portland cements. Its composition
varies depending on the Ca/Si ratio and on the presence of other ions such as aluminium (called CA-
S-H) or alkalis.
This thesis aimed to study the compositi ...
The reactivity of disordered, noncrystalline U(IV) species remains poorly characterized despite their prevalence in biostimulated sediments. Because of the lack of crystalline structure, noncrystalline U(IV) may be susceptible to oxidative mobilization und ...