Big BounceThe Big Bounce is a hypothesized cosmological model for the origin of the known universe. It was originally suggested as a phase of the cyclic model or oscillatory universe interpretation of the Big Bang, where the first cosmological event was the result of the collapse of a previous universe. It receded from serious consideration in the early 1980s after inflation theory emerged as a solution to the horizon problem, which had arisen from advances in observations revealing the large-scale structure of the universe.
Cosmological constantIn cosmology, the cosmological constant (usually denoted by the Greek capital letter lambda: Λ), alternatively called Einstein's cosmological constant, is the constant coefficient of a term that Albert Einstein temporarily added to his field equations of general relativity. He later removed it. Much later it was revived and reinterpreted as the energy density of space, or vacuum energy, that arises in quantum mechanics. It is closely associated with the concept of dark energy.
Organic reactionOrganic reactions are chemical reactions involving organic compounds. The basic organic chemistry reaction types are addition reactions, elimination reactions, substitution reactions, pericyclic reactions, rearrangement reactions, photochemical reactions and redox reactions. In organic synthesis, organic reactions are used in the construction of new organic molecules. The production of many man-made chemicals such as drugs, plastics, food additives, fabrics depend on organic reactions.
Non-standard cosmologyA non-standard cosmology is any physical cosmological model of the universe that was, or still is, proposed as an alternative to the then-current standard model of cosmology. The term non-standard is applied to any theory that does not conform to the scientific consensus. Because the term depends on the prevailing consensus, the meaning of the term changes over time. For example, hot dark matter would not have been considered non-standard in 1990, but would be in 2010.
Chain reactionA chain reaction is a sequence of reactions where a reactive product or by-product causes additional reactions to take place. In a chain reaction, positive feedback leads to a self-amplifying chain of events. Chain reactions are one way that systems which are not in thermodynamic equilibrium can release energy or increase entropy in order to reach a state of higher entropy. For example, a system may not be able to reach a lower energy state by releasing energy into the environment, because it is hindered or prevented in some way from taking the path that will result in the energy release.
HyperconjugationIn organic chemistry, hyperconjugation (σ-conjugation or no-bond resonance) refers to the delocalization of electrons with the participation of bonds of primarily σ-character. Usually, hyperconjugation involves the interaction of the electrons in a sigma (σ) orbital (e.g. C–H or C–C) with an adjacent unpopulated non-bonding p or antibonding σ* or π* orbitals to give a pair of extended molecular orbitals. However, sometimes, low-lying antibonding σ* orbitals may also interact with filled orbitals of lone pair character (n) in what is termed negative hyperconjugation.
Time-of-flight mass spectrometryTime-of-flight mass spectrometry (TOFMS) is a method of mass spectrometry in which an ion's mass-to-charge ratio is determined by a time of flight measurement. Ions are accelerated by an electric field of known strength. This acceleration results in an ion having the same kinetic energy as any other ion that has the same charge. The velocity of the ion depends on the mass-to-charge ratio (heavier ions of the same charge reach lower speeds, although ions with higher charge will also increase in velocity).
Void (astronomy)Cosmic voids (also known as dark space) are vast spaces between filaments (the largest-scale structures in the universe), which contain very few or no galaxies. The cosmological evolution of the void regions differs drastically from the evolution of the Universe as a whole: there is a long stage when the curvature term dominates, which prevents the formation of galaxy clusters and massive galaxies. Hence, although even the emptiest regions of voids contain more than ~15% of the average matter density of the Universe, the voids look almost empty to an observer.
Thermodynamic versus kinetic reaction controlThermodynamic reaction control or kinetic reaction control in a chemical reaction can decide the composition in a reaction product mixture when competing pathways lead to different products and the reaction conditions influence the selectivity or stereoselectivity. The distinction is relevant when product A forms faster than product B because the activation energy for product A is lower than that for product B, yet product B is more stable.
Mass spectral interpretationMass spectral interpretation is the method employed to identify the chemical formula, characteristic fragment patterns and possible fragment ions from the mass spectra. Mass spectra is a plot of relative abundance against mass-to-charge ratio. It is commonly used for the identification of organic compounds from electron ionization mass spectrometry. Organic chemists obtain mass spectra of chemical compounds as part of structure elucidation and the analysis is part of many organic chemistry curricula.
