Publication
Thermal activation and aging of a V2O5/WO3-TiO2 catalyst for the selective catalytic reduction of NO with NH3
Related publications (94)
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Davide Ferri, Oliver Kröcher, Rob Jeremiah G. Nuguid
Raw exhaust gases may contain notable levels of formaldehyde that can negatively impact the efficiency of after -treatment systems. In the selective catalytic reduction (SCR) of NOx over V2O5/WO3-TiO2, formaldehyde was found to react with NH3 to produce HC ...
ELSEVIER2021Operando diffuse reflectance infrared detection of cyanide intermediate species during the reaction of formaldehyde with ammonia over V2O(5)/ WO3-TiO2
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Hydrogen cyanide (HCN) is a highly poisonous gas that can form through the reaction between formaldehyde and ammonia (NH3) in the exhaust. While this detrimental side reaction has been the subject of recent catalytic studies under selective catalytic reduc ...
ELSEVIER2021Selective Catalytic Reduction of NO with NH3 on Cu-SSZ-13: Deciphering the Low and High-temperature Rate-limiting Steps by Transient XAS Experiments
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Cu-exchanged small-pore SSZ-13 catalysts have found wide use for the selective catalytic reduction (SCR) of nitrogen oxides from automotive exhaust gases. The transient working environment of the Cu-SSZ-13 catalyst during NH3-SCR requires studying the rate ...
WILEY-V C H VERLAG GMBH2020Engineering the ZrO2–Pd Interface for Selective CO2 Hydrogenation by Overcoating an Atomically Dispersed Pd Precatalyst
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Tailoring the interfacial sites between metals and metal oxides can be an essential tool in designing heterogeneous catalysts. These interfacial sites play a vital role in many renewable applications, for instance, catalytic CO2 reduction. Postsynthesis de ...
2020Catalytic Enantioselective Benzilic Ester Rearrangement
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We report the first examples of catalytic enantioselective benzilic ester rearrangement reaction. In the presence of a catalytic amount of Cu(OTf)(2) and a chiral box ligand under mild conditions, reaction of 2,3-diketoesters with alcohols afforded structu ...
WILEY-V C H VERLAG GMBH2020Palladium-Catalyzed Multicomponent Synthesis of Fully Substituted Alkylidene Furanones
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In the presence of a catalytic amount of Pd(OAc)(2) and XantPhos, the three-component reaction of ynones, imines, and aryl iodides affords fully substituted alkylidene-furan-3(2H)-ones via a sequence of the Mannich reaction followed by chemo- and regiosele ...
AMER CHEMICAL SOC2020Influence of N-heterocyclic carbenes (NHCs) on the hydrolysis of a diphosphene
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ROYAL SOC CHEMISTRY2020Thermal activation and aging of a V2O3/WO3-TiO2 catalyst for the selective catalytic reduction of NO with NH3
Davide Ferri, Oliver Kröcher, Adrian Marberger, Rob Jeremiah G. Nuguid
Real-world vanadium-based catalysts for the selective catalytic reduction (SCR) of NO with NH3 are occasionally exposed to high temperatures, which can induce catalyst aging. In this work, a 2.0 wt% V2O5/WO3-TiO2 catalyst based on commercial WO3-TiO2 was l ...
ELSEVIER SCIENCE BV2019Modulated Excitation Raman Spectroscopy of V2O5/TiO2: Mechanistic Insights into the Selective Catalytic Reduction of NO with NH3
Davide Ferri, Oliver Kröcher, Adrian Marberger, Rob Jeremiah G. Nuguid
We report the increased level of mechanistic information that Raman spectroscopy can provide when combined with modulated excitation experimentation. A V2O5/TiO2 catalyst for the selective catalytic reduction (SCR) of NO, was subjected to periodic NH3 puls ...
AMER CHEMICAL SOC2019Supported PtxPd1-x bimetallic nanoparticles on ionic liquid-functionalized SiO2@graphene oxide nanocomposite and its application as an effective multiphasic catalyst
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In this work, PtxPd1-x (x = 0, 0.5, and 1) nanoparticles (NPs) were synthesized on the surface of SiO2@graphene oxide which covered by 1-butyl-3-methylimidazolium hexafluorophosphate ([bmitn] PF6) ionic liquid (IL) layer. FT-IR spectroscopy, zeta potential ...
ELSEVIER SCIENCE BV2019