Publication

1,3-diethynylallenes (DEAs): enantioselective synthesis, absolute configuration, and chiral induction in 1,1,4,4-tetracyanobuta-1,3-dienes (TCBDs)

Pablo Rivera Fuentes
2008
Journal paper

Abstract

Optically active 1,3-diethynylallenes (DEAs) were prepd. by enantioselective Pd-mediated SN2'-type cross-coupling and their abs. configuration was detd. by X-ray anal. Addn. of tetracyanoethene (TCNE) to donor-substituted DEAs affords novel 1,1,4,4-tetracyanobutadiene (TCBDs)-based charge-transfer chromophores in high yield. CD spectroscopy reveals strong chiral induction from the optically pure allene into the directly adjacent TCBD moieties.

Official source

https://infoscience.epfl.ch/record/271797?ln=en

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1,3-diethynylallenes (DEAs): enantioselective synthesis, absolute configuration, and chiral induction in 1,1,4,4-tetracyanobuta-1,3-dienes (TCBDs)

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