A new spin on C60: Axially chiral, pushpull buta-1,3-diene chromophores conjugated to vicinally methylated fullerenes (see picture) have high barriers of rotation about their chiral axes. These high barriers allowed their optical resolution and the determination of the absolute configuration by comparison of experimental and calculated circular dichroism spectra. The methyl group is rigidly fixed upon the surface of the carbon sphere and is responsible for the high rotational barriers. (Figure Presented). © 2010 Wiley-VCH Verlag GmbH & Co. KGaA.
Hatice Altug, Felix Ulrich Richter, Yasaman Jahani, Rui Lu, Bang Hyun Lee, Ming-Lun Tseng, Longfang Ye
Majed Chergui, Oliviero Cannelli, Giulia Fulvia Mancini, Malte Oppermann, Camila Bacellar Cases Da Silveira, Dominik Kinschel, Christian David, Jérôme Lacour
Majed Chergui, Malte Oppermann, Jérôme Lacour