Advances in understanding cement hydration mechanisms
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Exposure of concrete to the atmosphere changes the microstructure of the cement paste. However, knowledge about the alteration of the porosity due to drying is typically not considered in deterioration processes of the hardened cement paste. The purpose of ...
The aim of this thesis is to understand the mechanisms underlying the main hydration peak and later ages of alite hydration; it proposes new mechanistic models for these two stages.Alite is the main constituent of Portland Cement (PC), and is responsible ...
Through a collaborative work established between CIDEM and the Laboratory of Construction Materials at EPFL, a new cementitious system based on a synergetic combination of calcined clay and limestone as Portland's clinker replacement was developed. The nov ...
Supplementary cementitious materials (SCMs) are currently used to replace part of the clinker to reduce the environmental impact of cement and to favor the use of local materials. Two representative SCM have been used in this work: slag and fly ash. Each o ...
High-performance concrete is sensitive to early-age cracking, mainly due to its rapidly-developing autogenous shrinkage. Autogenous shrinkage and internal relative humidity (RH) decrease are direct consequences of the emptying of capillary pores due to cem ...
At the turn of the 19th century, the production and use of concrete were limited by the unavailability of raw materials to produce good cement in several places. From that time onwards, the progress of chemistry and a number of empirical discoveries opened ...
This thesis investigates the replacement of Portland cement by addition of high amounts of calcined clays and limestone. Such ternary blends can become more ecological and economical binders to answer the worldwide housing shortage. It could be demonstrate ...
The modeling platform µic has been extended to study the hydration of cement based systems. It is shown that the hydration kinetics of alite can be described through the implementation of two mechanisms: a solution controlled dissolution (SCD) mechanism fo ...
Purpose This paper aims to develop a numerical, micromechanical model to predict the evolution of autogenous shrinkage of hydrating cement paste at early age (up to 7 days). Autogeneous shrinkage can be important in high-performance concrete characterized ...
Blended cements, where Portland cement clinker is partially replaced by supplementary cementitious materials (SCMs), provide the most feasible route for reducing carbon dioxide emissions associated with concrete production. However, lowering the clinker co ...
