Enhancing Hydrogen Evolution Activity of Au(111) in Alkaline Media through Molecular Engineering of a 2D Polymer
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Water-soluble lanthanide-containing coordination nanoparticles with a size around 4-5 nm were prepared by the growth confinement of the Tb-2(bdc)(3)(H2O)(4) three-dimensional network using an organic polymer; the terbium- and the europium-based objects pre ...
A series of cobalt complexes with macrocyclic imine ligands such as difluoroboryldiglyxomime and [14]-Tetraene-N4 are synthesized for electrochem. hydrogen evolution catalysis. The complexes catalyze the redn. of proton to dihydrogen at potentials in the r ...
Cobalt complexes supported by diglyoxime ligands of the type Co(dmgBF2)2(CH3CN)2 and Co(dpgBF2)2(CH3CN2) (where dmgBF2 is difluoroboryldimethylglyoxime and dpgBF2 is difluoroboryldiphenylglyoxime), as well as cobalt complexes with 1;143;-tetraene-N4 (Tim) ...
Since the beginning of the twenty-first century the limitations of the fossil age with regard to the continuing growth of energy demand, the peaking mining rate of oil, the growing impact of CO2 emissions on the environment and the dependency of the econom ...
Whereas pentylsodium in pentane mainly promotes a hydrogen/metal exchange reaction at the m- and p-position of phenylcyclopropane (I), both BuLi-KOCMe3 and Me3SiCH2K in THF convert I into 1-phenylcyclopropylpotassium. The latter adds smoothly to ethylene a ...
Compositional studies of electrode films based on RuO2-TiO2 mixts., prepd. by pyrolytic oxidn. of RuCl3.3H2O-diisopropoxybis(2,4-pentanedionato)titanium deposits show that these materials contain large amts. of carbon and hydrogen impurities. This evidence ...
Ion-bombarded polystyrene with a 0.5-keV Ar+ beam has been investigated by means of photoelectron spectroscopy performed with synchrotron radiation. After a dose of 10(15) ions/cm2 the evolution of the valence band of the bombarded sample towards an amorph ...
Rh NPs coated with a PVP-derived polymer, that combines several distinct protective interactions, exhibit superior thermal and catalytic stability compared to analogue NPs coated with PVP. ...
Blowing bubbles: Hydrogen evolution by proton reduction with [(C5Me5)2Fe] occurs at a soft interface between water and 1,2-dichloroethane (DCE). The reaction proceeds by proton transfer assisted by [(C5Me5)2Fe] across the water–DCE interface with subsequen ...
Due to the limiting amount of fossil fuel available and to the continuous growth of the world energy consumption, it becomes important to find alternative energy sources. Hydrogen produced by the photoelectrolysis of water is a perfect candidate as a clean ...