Publication

Open and Closed Radicals: Local Geometry around Unpaired Electrons Governs Magic-Angle Spinning Dynamic Nuclear Polarization Performance

Related publications (42)

Frobenius techniques in birational geometry

This is a survey for the 2015 AMS Summer Institute on Algebraic Geometry about the Frobenius type techniques recently used extensively in positive characteristic algebraic geometry. We first explain the basic ideas through simple versions of the fundamenta ...

2017

Searching for optimal conditions during one- and multi-dimensional solid-state NMR experiments in high static fields may require spinning the sample at frequencies above 40 kHz. This implies challenging requirements for heteronuclear spin decoupling. We ha ...

Elsevier2014

Decoupling of Magnetic Resonance Signals in Time and Frequency Domain

Nuclear magnetic resonance (NMR) was discovered in the first half of the 20th century. Today, neither analytical chemistry without NMR spectroscopy nor medical diagnostics without magnetic resonance imaging (MRI) could be imagined. A magnetic resonance sig ...

EPFL2013

Dynamic Studies through Control of Relaxation in NMR Spectroscopy

Nicola Salvi

In numerous biological processes that constitute the base of living organisms, protein function is fundamentally related to internal dynamics occurring on μs-ms time scales that can give rise to chemical exchange contributions to relaxation. In a heteronuc ...

EPFL2013

Direct Evaluation of the Hyperconjugative Interactions

Zhenhua Chen

Following the computational strategy proposed by Mulliken in 1939 (J. Chem. Phys. 7 (5), 339-352 (1939)) when the concept of hyperconjugation was coined, we evaluated the hyperconjugative stabilization energy in 1,1,1-trihaloethane using the block-localize ...

American Chemical Society2013

Spin echo NMR spectra without J modulation

Geoffrey Bodenhausen

The spin echo is the single most important building block in modern NMR spectroscopy, but echo modulation by scalar couplings J can severely complicate its use. We show for the first time that a general but unacknowledged solution to such complications alr ...

2012

This Letter shows that interleaved sequences of short pulses in the manner of 'Delays Alternating with Nutation for Tailored Excitation' (DANTE) with N = 1,2,3 . . . equidistant pulses per rotor period extending over K rotor periods can be used to excite, ...

Elsevier2012

Improving Sensitivity in Solid State NMR

Sensitivity in Nuclear Magnetic Resonance (NMR), especially in solid-state NMR, has always been a challenging and important issue and thus a motivation for new developments. The magnetic field B0, the gyromagnetic ratios of the observed nuclei, as well as ...

EPFL2012

Extending Timescales and Narrowing Linewidths in NMR

Geoffrey Bodenhausen, Aurélien Bornet, Pascal Miéville, Sami Jannin, Diego Carnevale, Paul Romeo Vasos, Simone Ulzega, Marc Anthony Caporini, Nicola Salvi, Martial Rey

Among the different fields of research in nuclear magnetic resonance (NMR) which are currently investigated in the Laboratory of Biomolecular Magnetic Resonance (LRMB), two subjects that are closely related to each other are presented in this article. On t ...

Schweizerische Chemische Gesellschaft2011

Probing the electrical properties of highly-doped Al:ZnO nanowire ensembles

Klaus Kern, Hagen Klauk

The analysis of transparent conducting oxide nanostructures suffers from a lack of high throughput yet quantitatively sensitive set of analytical techniques that can properly assess their electrical properties and serve both as characterization and diagnos ...

2010

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