Tuning the Size and Geometry of Heteroleptic Coordination Cages by Varying the Ligand Bent Angle
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What does a blind entity need in order to determine the geometry of the set of photocells that it carries through a changing lightfield? In this paper, we show that very crude knowledge of some statistical properties of the environment is sufficient for th ...
Nanostencils are used in dynamic mode to pattern on top of flexible substrates. As the stencil is moving during the material evaporation, the obtained structures are the convolution between the stencil trajectory and the apertures’ geometry. Variable-thick ...
Hexanuclear coordination cages of the formula [(C5Me4R)M(C7H3NO 4)]6 (M = Rh, Ir; R = Me, H) were obtained by stepwise reaction of [(C5Me4R)M(μ-Cl)Cl]2 with, first AgOAc and then pyridine-3,5-dicarboxylic acid. Crystallographic analyses show that the cages ...
The influence of the geometry, via the ratio L/W of the Hall cells and the geometrical correction factor G on several figures of merit regarding Hall sensors is analyzed, namely the sensitivity, Hall Voltage and power dissipated within the device. Experime ...
A novel palladium-catalyzed domino spirocyclization for the formation of spiropyrrolidine-3,3'-oxindoles is reported. Both Heck and aminopalladation are viable pathways and the route that occurs depends on the ligand used and 2-(2-MeC6H4)C6H4P(CMe3)2 is re ...
Climate has a direct impact on cities' energy flows due to the space conditioning (heating, cooling) needs of the buildings accommodated. This impact may be reinforced due to climate change and to the (so called) urban heat island effect. The corresponding ...
The title compound, Co(C20H23N3O2)(C5H11N) or [Co{(Me-sal)(2)dien}(pprdn)] BPh4, where (Me-sal) 2dien is 2,2'[1,1'-(3-azapentane-1,5-diyldinitrilo)diethylidyne]diphenolate and pprdn is piperidine, contains a pentadentate (Me-sal) 2dien ligand fu ...
Most of the number of sources estimation techniques use the well-known signal-subspace approach in which the number of dominant sources is deduced regarding the multiplicity of the lowest eigenvalues of the correlation matrix. In the at-worst determined ca ...
A novel ruthenium(II) compound, trans-cis-cis-[Ru(II)Cl-2(DMSO)(2)(2-amino-5-methyl-thiazole)(2)], (I), PMRu52 hereafter, that may be obtained from the previously described (cis and trans)[Ru(II)Cl-2(DMSO)(4)] complexes, was designed, synthesized and chara ...
A cyclic tetranuclear cyclometallated iridium(III) complex using cyanide anions as bridging ligands and displaying a tetrahedrally distorted square geometry has been obtained with high yield; photo- and electrochemical characterizations show that most inte ...