Anionic character of the conduction band of sodium chloride
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The anodic dissolution of 100Cr6 steel in neutral electrolytes containing sodium chloride and sodium nitrate was investigated potentiodynamically and galvanodynamically with a rotating disc electrode at room temperature. The total concentration of the mixe ...
A phenomenological model is proposed for a better understanding of the basic mechanisms of photoelectrochemical (PEC) cells. The main assumptions of the one-dimensional transient phenomenological model are: i) bulk recombination of the conduction band elec ...
Tuning of effective band gaps at insulator surfaces by adsorbed molecules is of fundamental interest but also technologically relevant for contact charging induced by adsorbed molecules like hydroxybenzoic acids. Our studies by density functional theory of ...
Using angle-resolved photoelectron spectroscopy we investigate the electronic valence band structure of the Si(331)-(12 × 1) surface reconstruction for which we recently proposed a structural model containing silicon pentamers as elementary structural buil ...
The defect levels of the nitrogen dangling bond at the Si/SiO2 interface are determined through a density-functional approach. The composition grading at the interface is modeled through crystalline and amorphous models of stoichiometric SiO2, nitrided SiO ...
The photoexcitation and photoionization dynamics of sodium atoms deposited on the surface of helium nanodroplets and aromatic molecules (aniline, phenol and toluene) embedded in the interior of droplets have been investigated by a variety of spectroscopic ...
2-Methylprop-2-ene-, prop-2-ene-, 1-methylprop-2-ene-, and (E)-but-2-enesulfonyl chlorides have been used as electrophilic partners in desulfinylative palladium- catalyzed C–C coupling with Grignard reagents and sodium salts of dimethyl malonate and methyl ...
Benzo-15-crown-5 functionalized polymer brushes prepared via surface-initiated atom transfer radical polymerization are used as the active layer in a potassium-selective quartz crystal microbalance sensor. The polymer brushes allow the selective detection ...
With the purpose of assessing the reactivity of chloride ions dissolved in ionic liquids (ILs), a relative scale for the solvation of chloride is given for a series of ILs based on the bis(trifluoromethane)sulfonimide ([Tf2N]) anion and differen ...
The coupling of the flow field flow fractionation to differential refractive index (DRI) and multi-angle laser light scattering detectors is a powerful tool for characterizing charged polysaccharides such as alginate. However, the correct interpretation of ...