Organic Chemistry and Synthesis Rely More and More upon Catalysts
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Alkene functionality can be found in the majority of natural products, drugs, catalysts and organic materials. Therefore, methods of C-C double bond formation constitute a cornerstone of organic synthesis. Selective formation of either (Z)- or (E)-isomer i ...
Vicinal amino alcohols and diamines are privileged motifs in organic chemistry. As such, they have been targets of choice for exploring and developing novel and more efficient strategies in organic synthesis. In this context, the difunctionalization of ole ...
To meet the future global energy demand - an estimated additional 10 terawatts (TWs) per year in 2050 - a diversification of energy sources and fuels is needed. Solar energy represents a prominent alternative energy source. An important material for these ...
The term functionalized isocyanides refers to all those isocyanides in which a neighbouring functional group can finely tune the reactivity of the isocyano group or can be exploited in post-functionalization processes. In this manuscript, we have reviewed ...
The chemistry of aromatic triazenes is well known, and has been explored for more than a century.
These compounds have emerged as very useful intermediates, because of their unique reactivity.
This functionality can notably be used to access many other fun ...
Computational studies of organic systems are frequently limited to static pictures that closely align with textbook style presentations of reaction mechanisms and isomerization processes. Of course, in reality chemical systems are dynamic entities where a ...
A new methodology for producing hyperpolarized C-13 nuclei in small organic systems via parahydrogen induced polarization (PHIP) is proposed: ADAPT (Alternating Delays Achieve Polarization Transfer). The theoretical foundation of the process is investigate ...
Atmospheric particulate matter (PM) has been associated with increased morbidity and mortality, reduced visibility, and is one of the least understood components of the climate system. Organic matter (OM) constitutes a substantial fraction (up to 80%) of P ...
Guidelines for measuring luminescence of inorganic compounds, metal complexes and organometallic compounds are described. Common textbooks and manuals describing these measurements are usually aimed for physical and/or organic chemists and are not always s ...
International Union of Pure and Applied Chemistry2016
1-Aryl-3,3-dialkyltriazenes have received considerable attention in the context of synthetic and medicinal chemistry. In contrast, the chemistry of other unsaturated triazenes is largely unexplored. The synthesis of 1-allenyltriazenes is described. This ne ...