Tandem effect of Ag@C@Cu catalysts enhances ethanol selectivity for electrochemical CO2 reduction in flow reactors
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Treatment of RO3SC6H4Me-4 with R1MgBr in THF over Li2CuCl4 at -78 Deg with slowly raising the temp. to room temp. gave, in good yields, the derivs. RR1 (R = e.g. Et, Ph, cyclohexyl, or octyl; R1 = Et, CMe3, Ph, cyclohexyl). [on SciFinder (R)] ...
Treating PhMe with BuLi in the presence of KOCMe3 gave PhCH2K, which on LiBr treatment was converted into 85% PhCH2Li, characterized with Me3SiCl as PhCH2SiMe3. Similarly, at -20 Deg H2C:CMe2 gave 80% H2C:CMeCH2Li converted by CO2 or ethylene oxide into H2 ...
During the anaerobic batch cultivation of Kluyveromyces fragilis on a complex medium contg. glucose (100 g/L), EtOH was produced at levels resulting in the inhibition of growth and EtOH formation. Continuous extn. of the EtOH using transmembrane distn. res ...