Marine isotope stage (MIS) 8 millennial variability stratigraphically identical to MIS 3
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We present a 650-year Antarctic ice core record of concentration and isotopic ratios (δ13C and δ18O) of atmospheric carbon monoxide. Concentrations decreased by ∼25% (14 parts per billion by volume) from the mid-1300s to the 1600s then recovered completely ...
American Association for the Advancement of Science (AAAS)1997
The alcoholate-induced dehydrochlorination of styryl chloride possibly occurs by the 3 different competing mechanisms: E2, E1cb, and E1cb-HBA an E1cb modification. These conclusions were confirmed by H-D exchange, isotope effects, order of reaction, and re ...
The presence of Zr isotope anomalies in the early solar system is demonstrated with the identification of Zr-92 excesses and Zr-96. deficits in several chondrites and the CAI Allende inclusions. The isotopic composition of Zr in carbonaceous, enstatite, an ...
Chemical zoning patterns in some iron, nickel metal grains from CH carbonaceous chondrites imply formation at temperatures from 1370 to 1270 kelvin by condensation from a solar nebular gas cooling at a rare of similar to 0.2 kelvin per hour. This cooling r ...
Long-term evolution of the Earth's water cycle is investigated to predict potential variations in the hydrogen stable isotope composition of seawater. Mass balance calculations are used to estimate the delta D value of the early ocean before storage of wat ...
Knowledge about the distribution of surfactants between aq. and reverse micellar phases as well as the assocn. of surfactants with proteins are of major importance for assessing the practical feasibility of protein extn. by reverse micellar systems. The qu ...
We have studied the synthesis and stability of the monooxygenase AlkB of Pseudomonas oleovorans in its natural host and in recombinant Escherichia coli. Three strains were investigated: the prototype strain P. oleovorans and the E. coli alk+ recombinants H ...
A threshold near 6.8 eV is obsd. for the dissocn. of H2O (and D2O) via the repulsive A(1B1) potential in rare gas matrixes. The threshold varies within 0.2 eV for exchange of Kr with Ar matrix, upon deuteration, and with temp. The observations are consiste ...
Isotope sepn. was demonstrated following the selective IR laser-induced photodissocn. of van der Waals clusters in a free jet. Irradn. of a natural abundance mixt. of SF6 isotopomers dild. in Ar with a 20-W cw CO2 laser gave overall enrichment factors >1.1 ...
The separation of hydrogen isotopes for applications such as nuclear fusion is a major challenge. Current technologies are energy intensive and inefficient. Nanoporous materials have the potential to separate hydrogen isotopes by kinetic quantum sieving, b ...