Exploring Photoredox-Catalyzed (Re)functionalizations with Core-Modified Benziodoxolones
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L-Lemonose, the glycosidic part of (–)-lemonomycin, has been synthesized in ten steps with 18% overall yield from Dthreonine. The key steps are a double, highly diastereoselective Grignard addition to a Weinreb amide and a chemoselective oxidation of a pri ...
A group of 12 architecture students from EPFL returned from the London Festival of Architecture (19 June-19 July 08), where their contribution, "Overflow", a structure that reacts to tides in the Thames River, was chosen as the best overall project among a ...
Given a principal bundle G hooked right arrow P -> B (each being compact, connected and oriented) and a G-invariant metric h(P) on P which induces a volume form mu(P), we consider the group of all unimodular automorphisms SAut(P, mu(P)) := {phi is an eleme ...
This thesis is divided in seven main chapters including an introduction about the state of the art in the field, four main chapters describing the main part of the work, a short insight on the implications of the presented results for other research projec ...
An unexpected C-C bond cleavage has been observed on pentafluorobenzoylamidoxlmes under mild basic conditions. This observation has been exploited to develop a new synthesis of 1,2,4-oxadiazol-5-ones from amidoximes using pentafluorobenzoyl chloride or tri ...
Fish organize themselves into schools as a way to defend against predators and improve foraging efficiency. In this work we develop a model for food foraging and explain how a school of fish can move as a group if every fish were to employ a distributed st ...
Mental rotation of body parts is influenced by specific sensory-motor information, and may be performed using an egocentric (subject-based) or an object-based mental transformation. Neurologically healthy volunteers were asked to verbally judge the lateral ...
The one-step conversion of cellulose to C6-alcs. via green and energy efficient approaches has, as far as we are aware, not been reported. Such a process presents a considerable challenge, the two key problems being (1) finding a suitable solvent that diss ...
Group communication is a programming abstraction that allows a distributed group of processes to provide a reliable service in spite of the possibility of failures within the group. The goal of the project was to improve the state of the art of group commu ...
The communication shows an alternative for introducing soil-structure interaction in the analysis of cut-and-cover tunnels. An uncoupled method is illustrated through two examples representative of the situations found in practice. The main features of eac ...
ELU-ULS 2006 - Symposium international sur les états limites ultimes des ouvrages géotechniques2006