Synthetic Receptors with Micromolar Affinity for Chloride in Water
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Elsevier2012
An experimental campaign supports a model named TransChlor for bringing liquid water moved by capillary suction and chloride ions into concrete. The principal objective of the experimental campaign is to represent conventional concretes under real conditio ...
An experimental campaign supports a model named TransChlor for bringing liquid water moved by capillary suction and chloride ions into concrete. The principal objective of the experimental campaign is to represent conventional concretes under real conditio ...
American Society of Civil Engineers2011
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Experimental work has been done to determine changes in the particle shape of portlandite grown in the presence of different ions. To quantify the experimentally observed changes in morphology a new analysis tool was developed, allowing the calculation of ...
Elsevier2011
Hexanuclear coordination cages of the formula [(C5Me4R)M(C7H3NO 4)]6 (M = Rh, Ir; R = Me, H) were obtained by stepwise reaction of [(C5Me4R)M(μ-Cl)Cl]2 with, first AgOAc and then pyridine-3,5-dicarboxylic acid. Crystallographic analyses show that the cages ...
EPFL2010
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The commercially available fluorescence dye 8-hydroxypyrene-1,3,6-trisulfonate (HPTS) can be used as a selective molecular probe for the detection of caffeine in aqueous solution. ...
A coumarin derivative was employed for the detection of biogenic amines in buffered aqueous solution by UV-Vis or fluorescence spectroscopy. Incorporated in a polymeric matrix, the dye can also be used for the optical detection of gaseous amines. ...
The recognition and sensing of aqueous chloride by synthetic receptors is a challenging task. Herein we apply the chemosensing ensemble methodology to optically detect chloride in water at near physiological pH. Variants based on two closely related recept ...
Photocatalytic degradation of phenol, nalidixic acid, mixture of pesticides, and another of emerging contaminants in water was mediated by TiO2 and iron oxide immobilized on functionalized polyvinyl fluoride films (PVFf-TiO2-Fe oxide) in a compound parabol ...
Caught in a trap! Fluorimetric chloride sensing in water is achieved by exploiting the changes in partition constant of a receptor complex in its bound and nonbound states. In the presence of chloride, the complex preferentially resides in the micelle pseu ...