Synthetic Receptors with Micromolar Affinity for Chloride in Water
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Hexanuclear coordination cages of the formula [(C5Me4R)M(C7H3NO 4)]6 (M = Rh, Ir; R = Me, H) were obtained by stepwise reaction of [(C5Me4R)M(μ-Cl)Cl]2 with, first AgOAc and then pyridine-3,5-dicarboxylic acid. Crystallographic analyses show that the cages ...
Experimental work has been done to determine changes in the particle shape of portlandite grown in the presence of different ions. To quantify the experimentally observed changes in morphology a new analysis tool was developed, allowing the calculation of ...
Elsevier2011
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This work introduces trifluorotoluene as an alternative organic solvent for studying charge transfer across liquid vertical bar liquid interfaces. In comparison with the most popular organic solvents in this field, 1,2-dichloroethane and nitrobenzene, trif ...
An experimental campaign supports a model named TransChlor for bringing liquid water moved by capillary suction and chloride ions into concrete. The principal objective of the experimental campaign is to represent conventional concretes under real conditio ...
An experimental campaign supports a model named TransChlor for bringing liquid water moved by capillary suction and chloride ions into concrete. The principal objective of the experimental campaign is to represent conventional concretes under real conditio ...
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The recognition and sensing of aqueous chloride by synthetic receptors is a challenging task. Herein we apply the chemosensing ensemble methodology to optically detect chloride in water at near physiological pH. Variants based on two closely related recept ...
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