Using Complex Hydrides for Hydrogen Storage and Direct Borohydride Fuel Cells for Electricity Production
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This thesis is devoted to the study of the catalytic activity of small supported metal clusters. The TiO2(110)-(1×1) supported platinum cluster activity towards CO oxidation, its correlation with the cluster morphology, support properties, and the cluster ...
Carbon dioxide and the carbonates, the available natural C-1 sources, can be easily hydrogenated into formic acid and formates in water; the rate of this reduction strongly depends on the pH of the solution. This reaction is catalysed by ruthenium(II) pre- ...
The widespread adoption of hydrogen as an energy carrier could bring significant benefits, but only if a number of currently intractable problems can be overcome. Not the least of these is the problem of storage, particularly when aimed at use onboard ligh ...
The prerequisite for widespread use of hydrogen as an energy carrier is the development of new materials that can safely store it at high gravimetric and volumetric densities. Metal borohydrides M(BH 4) n (n is the valence of metal M), in particular, have ...
Molybdenum sulfide materials had been shown as promising non-precious catalysts for hydrogen evolution. This paper describes the study of the promotional effect of certain transition metal ions on the activity of amorphous MoS3 films. Ternary metal sulfide ...
Kinetics and pathways of C60 reaction with hydrogen gas were studied in a broad temperature interval and over extended periods of time. Specifically, hydrogenation was monitored in situ at high temperature and high hydrogen pressure conditions using the gr ...
Formic acid, containing 4.4 wt% of hydrogen, is a non-toxic liquid at ambient temperature and therefore an ideal candidate as potential hydrogen storage material. Formic acid can be generated via catalytic hydrogenation of CO2 or bicarbonate in the presenc ...
This project involved the conversion of a British Waterways maintenance craft to a canal boat, powered by a combination of a solid-state hydrogen store, Proton Exchange Membrane (PEM) fuel cell, lead-acid battery pack and a high-efficiency, permanent magne ...
2,2′-Bipyridine (bipy) and an imidazolium-functionalized bipy ligand were used in the synthesis of palladium nanoparticles in water and in ionic liquid. The function of such ligands was twofold: first, as stabilizing agents to prevent the agglomeration of ...