Molecular switchA molecular switch is a molecule that can be reversibly shifted between two or more stable states. The molecules may be shifted between the states in response to environmental stimuli, such as changes in pH, light, temperature, an electric current, microenvironment, or in the presence of ions and other ligands. In some cases, a combination of stimuli is required. The oldest forms of synthetic molecular switches are pH indicators, which display distinct colors as a function of pH.
Conjugated systemIn theoretical chemistry, a conjugated system is a system of connected p-orbitals with delocalized electrons in a molecule, which in general lowers the overall energy of the molecule and increases stability. It is conventionally represented as having alternating single and multiple bonds. Lone pairs, radicals or carbenium ions may be part of the system, which may be cyclic, acyclic, linear or mixed. The term "conjugated" was coined in 1899 by the German chemist Johannes Thiele.
Link groupIn knot theory, an area of mathematics, the link group of a link is an analog of the knot group of a knot. They were described by John Milnor in his Ph.D. thesis, . Notably, the link group is not in general the fundamental group of the link complement. The link group of an n-component link is essentially the set of (n + 1)-component links extending this link, up to link homotopy. In other words, each component of the extended link is allowed to move through regular homotopy (homotopy through immersions), knotting or unknotting itself, but is not allowed to move through other components.
Hopf linkIn mathematical knot theory, the Hopf link is the simplest nontrivial link with more than one component. It consists of two circles linked together exactly once, and is named after Heinz Hopf. A concrete model consists of two unit circles in perpendicular planes, each passing through the center of the other. This model minimizes the ropelength of the link and until 2002 the Hopf link was the only link whose ropelength was known. The convex hull of these two circles forms a shape called an oloid.
