Electrolyte engineering via ether solvent fluorination for developing stable non-aqueous lithium metal batteries
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A new generation of high power Li-ion batteries that avoid carbon as anodic material replacing it with the spinel Li4Ti5O12 has been studied in this work. For these new Li-ion cells new electrolyte compositions can be considered. The main work of this thes ...
Complexes of molecular LiF and LiFHF were synthesized using the metallamacrocyclic receptors (cymene)Ru-(C5H3NO2) (1), (CpRh)-Rh-*(C5H3NO2) (2), and (CpIr)-Ir-*(C5H3NO2) (3). LiBF4 complexes of 1-3 were prepared and subsequently treated with ...
Spark assisted chemical engraving (SACE) is an unconventional micromachining technology based on electrochemical discharge phenomena for glass and various ceramics. The limits of SACE with respect to small dimensions in the particular case of glass are exp ...
For the development of an elec. rechargeable zinc/air battery, La0.6Ca0.4CoO3-catalyzed (perovskite) bifunctional oxygen electrodes and pasted zinc electrodes were prepd. and tested in a monopolar zinc/oxygen cell. In addn., a bipolar Zn/oxygen stack was t ...
With the aim of improving the rate capability and the safety of nanocrystalline Li4Ti5O12-based high power lithium ion batteries, two high boiling point nitrile-based electrolytes namely, 3-ethoxypropionitrile (CH3CH2OCH2CH2CN, EPN)/1 M LiTFSI and 3-(2,2,2 ...
A high power density and high capacity primary or secondary electrochemical generator in which at least one electrode (1,2) is composed of an electrically active solid material, said electrode having a mesoporous texture forming a bicontinuous junction of ...
The reaction of FePS3 single crystals with a 1.6M n-butyl lithium solution in n-hexane has been followed through de electrical conductivity measurements as a function of the intercalation time. In order to investigate the influence of lithium insertion on ...
The capacitance of monolayer-protected gold nanoclusters (MPCs), CMPC, in solution has been theoretically reconsidered from an electrostatic viewpoint, in which an MPC is considered as an isolated charged sphere within two dielectric layers, the intrinsic ...
A comprehensive theoretical basis for understanding electrowetting is now available. It shows that it is possible to effect drastic shape changes in electrolyte droplets immersed in another (immiscible) electrolyte. ...
A SOFC, with a solid electrolyte layer and at least one anode layer constituting a stratified structure. The anode layer incorporates a twice substituted lanthanide chromite, substituted by Sr on A sites and by Ni or Cu on B sites. The stratified structure ...