Voltage-driven Reactivity of Liquid Ga and CuGa Nanoparticles for Electrocatalytic CO2 Reduction and Synthesis
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We report on the development of electrochemical etching technology for the production of multilayer porous structures |(MPS) allowing one to fabricate Bragg reflectors on the basis of GaN bulk substrates grown by Hydride Vapor Phase Epitaxy |(HVPE). The fo ...
The depletion of carbon-based fossil fuels and the rise in atmospheric carbon dioxide concentration will force an inevitable change in the future global energy landscape. CO2 reduction presents the advantages of decreasing its atmospheric concentration and ...
Metal organic supramolecular chemistry on surfaces has matured to a point where its underlying growth mechanisms are well understood and structures of defined coordination environments of metal atoms can be synthesized in a controlled and reproducible proc ...
A rapidly growing population and industrialization have caused the exploitation of natural resources in keeping with fossil fuels shortage. Due to the combustion of fossil fuels, the concentration of CO2 in the earth's atmosphere, which is a potent greenho ...
This thesis deals with the electrocatalytic properties of two-dimensional metal organic coordination networks (2D-MOCNs) self-assembled on electrode surfaces and catalytic activity of 2D-MOCNs is demonstrated for the first time. The low-coordinated metal c ...
Miniaturized, low temperature Solid Oxide Fuel Cells (SOFCs) that operate below 600 °C are promising for supplying electrical power to portable devices. Thin electrolyte membranes of less than one micrometer thickness have been shown to yield reasonable po ...
One central aim of nanotechnology is the creation and exploitation of nanostructured materials with pre-programmed architecture and properties. The fabrication of functional nanostructures relies on versatile protocols of synthetic chemistry enabling the p ...
Thermolysis of the nitride-bridged diuranium(IV) complex Cs{(-N)U(OSi((OBu)-Bu-t)(3))(3)} (1) showed that the bridging nitride behaves as a strong nucleophile, promoting N-C bond formation by siloxide ligand fragmentation to yield an imido-bridged sil ...
Controlled mixtures of novel Mg-based metal-organic frameworks (MOFs) were prepared, with H+ or K+ as counterions. A linear relation was found between synthesis pH and K/H ratio in the resultant mixture, establishing the tunability of the synthesis. Upon p ...
Pure gallium and pure boron (PureGaB) Ge-on-Si photodiodes were fabricated in a CMOS compatible process and operated in linear and avalanche mode. Three different pixel geometries with very different area-to-perimeter ratios were investigated in linear arr ...