CyanideIn chemistry, a cyanide () is a chemical compound that contains a functional group. This group, known as the cyano group, consists of a carbon atom triple-bonded to a nitrogen atom. In inorganic cyanides, the cyanide group is present as the cyanide anion . This anion is extremely poisonous. Soluble salts such as sodium cyanide (NaCN) and potassium cyanide (KCN) are highly toxic. Hydrocyanic acid, also known as hydrogen cyanide, or HCN, is a highly volatile liquid that is produced on a large scale industrially.
Crystallographic databaseA crystallographic database is a database specifically designed to store information about the structure of molecules and crystals. Crystals are solids having, in all three dimensions of space, a regularly repeating arrangement of atoms, ions, or molecules. They are characterized by symmetry, morphology, and directionally dependent physical properties. A crystal structure describes the arrangement of atoms, ions, or molecules in a crystal.
Potassium ferrocyanidePotassium ferrocyanide is the inorganic compound with formula K4[Fe(CN)6]·3H2O. It is the potassium salt of the coordination complex [Fe(CN)6]4−. This salt forms lemon-yellow monoclinic crystals. In 1752, the French chemist Pierre Joseph Macquer (1718–1784) first reported the preparation of potassium ferrocyanide, which he achieved by reacting Prussian blue (iron(III) ferrocyanide) with potassium hydroxide. Potassium ferrocyanide is produced industrially from hydrogen cyanide, ferrous chloride, and calcium hydroxide, the combination of which affords Ca2[Fe(CN)6]·11H2O.
Black bodyA black body or blackbody is an idealized physical body that absorbs all incident electromagnetic radiation, regardless of frequency or angle of incidence. The radiation emitted by a black body in thermal equilibrium with its environment is called black-body radiation. The name "black body" is given because it absorbs all colors of light. In contrast, a white body is one with a "rough surface that reflects all incident rays completely and uniformly in all directions.
Kirchhoff's law of thermal radiationIn heat transfer, Kirchhoff's law of thermal radiation refers to wavelength-specific radiative emission and absorption by a material body in thermodynamic equilibrium, including radiative exchange equilibrium. It is a special case of Onsager reciprocal relations as a consequence of the time reversibility of microscopic dynamics, also known as microscopic reversibility. A body at temperature T radiates electromagnetic energy.
Chemical process modelingChemical process modeling is a computer modeling technique used in chemical engineering process design. It typically involves using purpose-built software to define a system of interconnected components, which are then solved so that the steady-state or dynamic behavior of the system can be predicted. The system components and connections are represented as a process flow diagram. Simulations can be as simple as the mixing of two substances in a tank, or as complex as an entire alumina refinery.
Wien's displacement lawWien's displacement law states that the black-body radiation curve for different temperatures will peak at different wavelengths that are inversely proportional to the temperature. The shift of that peak is a direct consequence of the Planck radiation law, which describes the spectral brightness or intensity of black-body radiation as a function of wavelength at any given temperature. However, it had been discovered by Wilhelm Wien several years before Max Planck developed that more general equation, and describes the entire shift of the spectrum of black-body radiation toward shorter wavelengths as temperature increases.
FerrousIn chemistry, the adjective ferrous indicates a compound that contains iron(II), meaning iron in its +2 oxidation state, possibly as the divalent cation Fe2+. It is opposed to ferric, or iron(III), meaning iron in its +3 oxidation state, such as the trivalent cation Fe3+. This usage has been largely replaced by the IUPAC nomenclature, which calls for the oxidation state being indicated by Roman numerals in parentheses, such as iron(II) oxide for ferrous oxide (FeO), iron(III) oxide for ferric oxide (Fe2O3), and iron(II,III) oxide for the oxide that contains both forms of iron.
Light-secondThe light-second is a unit of length useful in astronomy, telecommunications and relativistic physics. It is defined as the distance that light travels in free space in one second, and is equal to exactly 299 792 458 metres (approximately 983 571 055 ft). Just as the second forms the basis for other units of time, the light-second can form the basis for other units of length, ranging from the light-nanosecond (299.8mm or just under one international foot) to the light-minute, light-hour and light-day, which are sometimes used in popular science publications.
