Ion Adsorption Enhances Apparent Nonelectrostatic Attraction between Monomers in Polyelectrolyte Brushes
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Thin coatings applied to surfaces dramatically improve the properties of materials. Thus, they have found application in a broad variety of areas including biomedicine, nanotechnology, bioelectronics and optics, amongst others. Polymer brushes prepared via ...
EPFL2016
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Surface-grafting thermoresponsive polymers allows the preparation of thin polymer brush coatings with surface properties that can be manipulated by variation of temperature. In most instances, thermoresponsive polymer brushes are produced using polymers th ...
The shape of a polymer plays an important role in determining its interactions with other molecules and with the environment, and is in turn affected by both of them. As a consequence, in the literature the shape properties of a chain in many different con ...
2017
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We reveal some of the key mechanisms during charge generation in polymer:fullerene blends exploiting our well-defined understanding of the microstructures obtained in pBTTT:PCBM systems via processing with fatty acid methyl ester additives. Based on ultraf ...
Organic photovoltaics will be one of the corner stones in solving the increasing world's energy demand issue. For this reason, a better understanding of the detailed mechanisms involved in energy conversion in the employed nanostructured materials is still ...
We have used a femtosecond-resolved spectroscopic technique based on the Stark effect (electromodulated differential absorption) in order to investigate free charge generation and charge drift in solar cell devices of neat conjugated polymer pBTTT and in i ...
Spie-Int Soc Optical Engineering2015
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Solid-state dye-sensitized solar cells (sDSCs) are devoid of such issues as electrolyte evaporation or leakage and electrode corrosion, which are typical for traditional liquid electrolyte-based DSCs. Poly(3,4-ethylenedioxythiophene) (PEDOT) is one of the ...
Surface-initiated polymerization represents a versatile strategy to modify a diverse range of materials with thin, functional polymer coatings. While in many cases the desired functional groups can be directly incorporated via (co)polymerization of the app ...
Adhesion towards glass and interfacial healing of partially supramolecular hybrid polymer networks featuring a range of H-bdnds content were investigated through two dedicated adhesion test methods. In a first series of tests, adhesion strength was measure ...
Mesoscopic simulations of star polymer melts adsorbed onto solid surfaces are performed using the dissipative particle dynamics (DPD) method. A set of parameters is developed to study the low functionality star polymers under shear. The use of a new bond-a ...