Contrasting Views of the Electric Double Layer in Electrochemical CO2 Reduction: Continuum Models vs Molecular Dynamics
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This paper reports on the fabrication and experimental characterisation of improved design AC eletroosmotic micropumps. Since the first study and analysis of AC electroosmosis by Ramos et al. [1], many devices have been fabricated and tested [2]. The basic ...
Adsorption of charged species at the interface between two immiscible electrolyte solutions (ITIES) is simulated taking into account both the mutual influence between the potential dependent surface excess charge and the potential distribution between the ...
A method for the fabrication of metallic nanoparticles in large quantities by electrochemical discharges is presented. In an aqueous electrolyte, large current density (similar to 1 A/mm(2) at similar to 20 V) leads to the formation of a 'gas film' around ...
Synthetic boron-doped diamond (BDD) thin film is an electrode material with high chemical and dimensional stability, low background current and a very wide potential window of water stability. Upon anodic polarization, BDD generates hydroxyl radicals that ...
A method to create an array of sub-5 nm nanogaps with self-aligned holes in a protective polymer overlayer is presented. The parallel formation of the nanogaps, intended for electrical sensing of biomolecules in an aqueous environment, is achieved by elect ...
The tribocorrosion behavior of tungsten sliding against an alumina ball was evaluated in sulfuric acid under applied electrode potential. Surface chemistry of worn and unworn surfaces was evaluated using XPS and AES. Quasi-potentiostatic polarization curve ...
The key-point for the development of an amperometric sensor is the immobilization of the enzyme. In the present work we use biosensors based on glucose oxidase (GOD) onto electrodes nanostructured with carbon nanotubes (CNT), to be employed in cell culture ...
Iridium dioxide electrodes form part of the dimensionally stable anodes (DSA®) and this electrode material is widely used in many industrial processes namely water electrolysis, metal electro-winning, cathodic protection and electro-organic synthesis due t ...
Dimensionally Stable Anodes (DSA®) are electrodes composed of a metal support and an oxide coating (catalyst). Particularly in this thesis, the Ti/IrO2 electrode was used for the study of the fraction of the surface which participates effectively in the in ...
The tribocorrosion behaviour of overlay welded Ni-Cr 625 alloy sliding against alumina in 0.5 M H2SO4 and 0.5 M HNO3 solutions under potentiostatic conditions was investigated. The passivation of the samples in the two electrolytes at different potentials ...