Carbon dioxide hydrogenation to methanol at low pressure and temperature
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The homogeneous hydrogenation of carbon dioxide into formate anion has been investigated in aqueous solution, using water soluble ruthenium(II)-phosphine (meta-monosulphonated triphenylphosphine, TPPMS; and 1,3,5-triaza-7-phosphaadamantane, PTA) complexes ...
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The water-soluble Ru(II)-phosphine complex, [{RuCl2(mTPPMS)(2)}(2)] was found a suitable catalyst for the hydrogenation of NaHCO3 to NaHCO2 in aqueous solution under mild conditions with catalyst turnover frequencies (TOFs) in the range of 35-50 h(-1) at 5 ...
The reactivity of the cluster family [Ru-3(CO)(12-x)(L)x] (in which L = PMe3, PMe2Ph, PPh3 and PCy3, x = 1 - 3) towards hydrogen is described. When x=2, three isomers of [Ru-3(H)(mu-H)(CO)(9)(L)(2)] are formed, which differ in the arrangement of their equa ...
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