Publications related to A nearly planar water sheet sandwiched between strontium-imidazolium carboxylate coordination polymers

Crystal structure of [NBu4](2)[Pd-2{C-4(COOMe)(4)}(2)(mu-OH)(2)] determined ab initio by charge flipping

The crystal structure of bis(tetra-n-butylammonium)bis(mu(2)-hydroxo)-bis(1,2,3,4-tetrakis(methoxycarbonyl)-1,3-butadiene-1,4-diyl)-di-palladium, NBu4[Pd-2{C-4(COOMe)(4)}(2) (mu-OH)(2)], was determined ab initio by X-ray single-crystal diffractometry ...

2009

Validating the model of a (3+1)-dimensional incommensurately modulated structure as generator of a family of compounds for the Eu2(MoO4)3 scheelite structure

Gervais Chapuis, Alla Arakcheeva, Philip Pattison, Jorge Martinez Garcia

The previously proposed model postulating that the incommensurately modulated KNd(MoO

_4

)

_2

structure can act as a generator of the scheelite family members is validated here by refining the crystal structure of europium molybdate, Eu

_2

(MoO

_4

)

_3

. ...

2009

Switch peptide via Staudinger reaction

Hilal Lashuel

A new transformation based on the Staudinger reaction is described, and its application in the design of a novel switch element to control peptide folding is demonstrated. We found that the azide switch is activated rapidly in water to promote acyl transfe ...

2008

Optical Kerr effect studies of the dynamics of confined water

Majed Chergui, Frank van Mourik, Erwin Portuondo Campa

Time resolved optical Kerr effect measurements have been used to det. the orientational dynamics of water in the pores of ZrO2 nanostructured films. We demonstrate that local heating effects can safely be ignored and present our results which are manifestl ...

2008

Selective removal of acetone and butan-1-ol from water with supported ionic liquid-polydimethylsiloxane membrane by pervaporation

Paul Joseph Dyson, Zhaofu Fei

The use of ionic liq.-polymer in supported ultrafiltration membrane in vacuum pervaporation has been verified. The ultrafiltration membranes were impregnated by two ionic liqs. (1-ethenyl-3-ethyl-imidazolium hexafluorophosphate and tetrapropylammonium tetr ...

2008

Sensor technologies based on a cellulose supported platform

Mohammad Khaja Nazeeruddin

A simple approach to sensor development based on encapsulating a probe molecule in a cellulose support followed by regeneration from an ionic liquid solution is demonstrated here by the codissolution of cellulose and 1-(2-pyridylazo)-2- naphthol in 1-butyl ...

2007

Synthesis, crystal structures and spectra of Hg(II)-1,2-bis(diphenylphosphino)ethane monoxide complexes: Monomer and polymer formation

The reaction of mercury(II) halides with 1,2-bis(diphenylphosphino)ethane monoxide (dppeO) in 1:1 molar ratio yielded P,O-coordinated polymers having the empirical formula [HgX2(dppeO)]n [X = Cl (1), Br (2), I (3)]. In contrast, the reaction between the sa ...

2007

A strategy for the synthesis of transition-metal nanoparticles and their transfer between liquid phases

Paul Joseph Dyson, Zhaofu Fei, Wee Han Ang, Dongbin Zhao

Nanoparticles can be stabilized by an ionic liq. polymer (ILP) composed of imidazolium units incorporating a hydrophobic benzyl group. The resulting gold, platinum, and palladium nanoparticles can be efficiently transferred from water to ionic liqs. by exc ...

2006

Fluorinated β-Diketones for the Extraction of Lanthanide Ions: Photophysical Properties and Hydration Numbers of Their EuIII Complexes

Jean-Claude Bünzli, Anne-Sophie Chauvin, Frédéric Gumy

Tris(β-diketonato)europium(III) with a series of variably fluorinated ligands derived from 3,5-heptanedione were synthesised with the aim of determining their hydration state under extraction conditions. The number of coordinated water molecules was determ ...

2006

Cyclosporin A prodrugs: design, synthesis and biophysical properties

Annelise Carrupt, Arnaud Hamel

The cyclic undecapeptide cyclosporin A (CsA) has a remarkable spectrum of diverse biological activities, including anti-inflammatory, antifungal, antiparasitic as well as immunosuppressive activities. However, the low water solubility of this drug is a ser ...

2004

A nearly planar water sheet sandwiched between strontium-imidazolium carboxylate coordination polymers

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Crystal structure of [NBu4](2)[Pd-2{C-4(COOMe)(4)}(2)(mu-OH)(2)] determined ab initio by charge flipping

Validating the model of a (3+1)-dimensional incommensurately modulated structure as generator of a family of compounds for the Eu2(MoO4)3 scheelite structure

Switch peptide via Staudinger reaction

Optical Kerr effect studies of the dynamics of confined water

Selective removal of acetone and butan-1-ol from water with supported ionic liquid-polydimethylsiloxane membrane by pervaporation

Sensor technologies based on a cellulose supported platform

Synthesis, crystal structures and spectra of Hg(II)-1,2-bis(diphenylphosphino)ethane monoxide complexes: Monomer and polymer formation

A strategy for the synthesis of transition-metal nanoparticles and their transfer between liquid phases

Fluorinated β-Diketones for the Extraction of Lanthanide Ions: Photophysical Properties and Hydration Numbers of Their EuIII Complexes

Cyclosporin A prodrugs: design, synthesis and biophysical properties

Switch peptide via Staudinger reaction

Synthesis, crystal structures and spectra of Hg(II)-1,2-bis(diphenylphosphino)ethane monoxide complexes: Monomer and polymer formation

Validating the model of a (3+1)-dimensional incommensurately modulated structure as generator of a family of compounds for the Eu2(MoO4)3 scheelite structure

Optical Kerr effect studies of the dynamics of confined water

Cyclosporin A prodrugs: design, synthesis and biophysical properties

Selective removal of acetone and butan-1-ol from water with supported ionic liquid-polydimethylsiloxane membrane by pervaporation

Crystal structure of [NBu4](2)[Pd-2{C-4(COOMe)(4)}(2)(mu-OH)(2)] determined ab initio by charge flipping

A strategy for the synthesis of transition-metal nanoparticles and their transfer between liquid phases

Fluorinated β-Diketones for the Extraction of Lanthanide Ions: Photophysical Properties and Hydration Numbers of Their EuIII Complexes

Sensor technologies based on a cellulose supported platform