Are you an EPFL student looking for a semester project?
Work with us on data science and visualisation projects, and deploy your project as an app on top of Graph Search.
Publication
Are you an EPFL student looking for a semester project?
Work with us on data science and visualisation projects, and deploy your project as an app on top of Graph Search.
The homo- and heterobimetallic complexes [CpRu(m-Cl)3-ML] [LM = (C6H6)Ru, (cymene)Ru, (1,3,5-C6H3iPr3)Ru, CpRh, CpIr] were prepd. by reaction of [CpRu(m-OMe)]2 with Me3SiCl and subsequent addn. of [LMCl2]2. The complexes [CpRu(m-Cl)3Ru(cymene)] and [CpRu(m-Cl)3-IrCp*] were characterized by single-crystal X-ray analyses. In crossover expts. with [CpRh(m-Cl)3RuCl(PPh3)2] and [CpRu(m-Cl)3Ru(1,3,5-C6H3iPr3)] in CD2Cl2, a dynamic equil. with the complexes [CpRh(m-Cl)3RuCp] and [(1,3,5-C6H3iPr3)Ru(m-Cl)3RuCl(PPh3) 2] was rapidly established, demonstrating the kinetic lability of the triple chloro bridge. Upon reaction of [CpRh(m-Cl)3RuCp] with benzene, the ionic complex [CpRu(C6H6)][CpRhCl3] was formed, which was characterized by X-ray crystallog.
, ,
, ,