Cathodic protectionCathodic protection (CP; kaeˈTQdIk) is a technique used to control the corrosion of a metal surface by making it the cathode of an electrochemical cell. A simple method of protection connects the metal to be protected to a more easily corroded "sacrificial metal" to act as the anode. The sacrificial metal then corrodes instead of the protected metal. For structures such as long pipelines, where passive galvanic cathodic protection is not adequate, an external DC electrical power source is used to provide sufficient current.
Tafel equationThe Tafel equation is an equation in electrochemical kinetics relating the rate of an electrochemical reaction to the overpotential. The Tafel equation was first deduced experimentally and was later shown to have a theoretical justification. The equation is named after Swiss chemist Julius Tafel." It describes how the electrical current through an electrode depends on the voltage difference between the electrode and the bulk electrolyte for a simple, unimolecular redox reaction ".
Platinum blackPlatinum black (Pt black) is a fine powder of platinum with good catalytic properties. The name of platinum black is due to its black color. It is used in many ways; as a thin film electrode, a fuel cell membrane catalyst, or as a catalytic ignition of flammable gases for "self-lighting' gas lamps, ovens, and stove burners. Platinum black is widely used as a thin film covering solid platinum metal, forming platinum electrodes for applications in electrochemistry.
Butler–Volmer equationIn electrochemistry, the Butler–Volmer equation (named after John Alfred Valentine Butler and Max Volmer), also known as Erdey-Grúz–Volmer equation, is one of the most fundamental relationships in electrochemical kinetics.
OverpotentialIn electrochemistry, overpotential is the potential difference (voltage) between a half-reaction's thermodynamically-determined reduction potential and the potential at which the redox event is experimentally observed. The term is directly related to a cell's voltage efficiency. In an electrolytic cell the existence of overpotential implies that the cell requires more energy than thermodynamically expected to drive a reaction. In a galvanic cell the existence of overpotential means less energy is recovered than thermodynamics predicts.
Vacuum depositionVacuum deposition , also known as vacuum coating or thin-film deposition, is a group of processes used to deposit layers of material atom-by-atom or molecule-by-molecule on a solid surface. These processes operate at pressures well below atmospheric pressure (i.e., vacuum). The deposited layers can range from a thickness of one atom up to millimeters, forming freestanding structures. Multiple layers of different materials can be used, for example to form optical coatings.
1 − 2 + 3 − 4 + ⋯In mathematics, 1 − 2 + 3 − 4 + ··· is an infinite series whose terms are the successive positive integers, given alternating signs. Using sigma summation notation the sum of the first m terms of the series can be expressed as The infinite series diverges, meaning that its sequence of partial sums, (1, −1, 2, −2, 3, ...), does not tend towards any finite limit. Nonetheless, in the mid-18th century, Leonhard Euler wrote what he admitted to be a paradoxical equation: A rigorous explanation of this equation would not arrive until much later.
Aqua regiaAqua regia (ˈreɪɡiə,_ˈriːdʒiə; from Latin, literally "regal water" or "royal water") is a mixture of nitric acid and hydrochloric acid, optimally in a molar ratio of 1:3. Aqua regia is a fuming liquid. Freshly prepared aqua regia is colorless, but it turns yellow, orange or red within seconds from the formation of nitrosyl chloride and nitrogen dioxide. It was named by alchemists because it can dissolve the noble metals gold and platinum, though not all metals.
Platinum nanoparticlePlatinum nanoparticles are usually in the form of a suspension or colloid of nanoparticles of platinum in a fluid, usually water. A colloid is technically defined as a stable dispersion of particles in a fluid medium (liquid or gas). Spherical platinum nanoparticles can be made with sizes between about 2 and 100 nanometres (nm), depending on reaction conditions. Platinum nanoparticles are suspended in the colloidal solution of brownish-red or black color. Nanoparticles come in wide variety of shapes including spheres, rods, cubes, and tetrahedra.
Native metalA native metal is any metal that is found pure in its metallic form in nature. Metals that can be found as native deposits singly or in alloys include aluminium, antimony, arsenic, bismuth, cadmium, chromium, cobalt, indium, iron, manganese, molybdenum, nickel, niobium, rhenium, selenium, tantalum, tellurium, tin, titanium, tungsten, vanadium, and zinc, as well as the gold group (gold, copper, lead, aluminium, mercury, silver) and the platinum group (platinum, iridium, osmium, palladium, rhodium, ruthenium).
