Square planar molecular geometryThe square planar molecular geometry in chemistry describes the stereochemistry (spatial arrangement of atoms) that is adopted by certain chemical compounds. As the name suggests, molecules of this geometry have their atoms positioned at the corners. Numerous compounds adopt this geometry, examples being especially numerous for transition metal complexes. The noble gas compound xenon tetrafluoride adopts this structure as predicted by VSEPR theory.
Ring (mathematics)In mathematics, rings are algebraic structures that generalize fields: multiplication need not be commutative and multiplicative inverses need not exist. In other words, a ring is a set equipped with two binary operations satisfying properties analogous to those of addition and multiplication of integers. Ring elements may be numbers such as integers or complex numbers, but they may also be non-numerical objects such as polynomials, square matrices, functions, and power series.
Local ringIn mathematics, more specifically in ring theory, local rings are certain rings that are comparatively simple, and serve to describe what is called "local behaviour", in the sense of functions defined on varieties or manifolds, or of algebraic number fields examined at a particular place, or prime. Local algebra is the branch of commutative algebra that studies commutative local rings and their modules. In practice, a commutative local ring often arises as the result of the localization of a ring at a prime ideal.
Ring homomorphismIn ring theory, a branch of abstract algebra, a ring homomorphism is a structure-preserving function between two rings. More explicitly, if R and S are rings, then a ring homomorphism is a function f : R → S such that f is: addition preserving: for all a and b in R, multiplication preserving: for all a and b in R, and unit (multiplicative identity) preserving: Additive inverses and the additive identity are part of the structure too, but it is not necessary to require explicitly that they too are respected, because these conditions are consequences of the three conditions above.
Quotient ringIn ring theory, a branch of abstract algebra, a quotient ring, also known as factor ring, difference ring or residue class ring, is a construction quite similar to the quotient group in group theory and to the quotient space in linear algebra. It is a specific example of a quotient, as viewed from the general setting of universal algebra. Starting with a ring R and a two-sided ideal I in R, a new ring, the quotient ring R / I, is constructed, whose elements are the cosets of I in R subject to special + and ⋅ operations.
Molecular geometryMolecular geometry is the three-dimensional arrangement of the atoms that constitute a molecule. It includes the general shape of the molecule as well as bond lengths, bond angles, torsional angles and any other geometrical parameters that determine the position of each atom. Molecular geometry influences several properties of a substance including its reactivity, polarity, phase of matter, color, magnetism and biological activity. The angles between bonds that an atom forms depend only weakly on the rest of molecule, i.
18-electron ruleThe 18-electron rule is a chemical rule of thumb used primarily for predicting and rationalizing formulas for stable transition metal complexes, especially organometallic compounds. The rule is based on the fact that the valence orbitals in the electron configuration of transition metals consist of five (n−1)d orbitals, one ns orbital, and three np orbitals, where n is the principal quantum number. These orbitals can collectively accommodate 18 electrons as either bonding or non-bonding electron pairs.
Catenary ringIn mathematics, a commutative ring R is catenary if for any pair of prime ideals p, q, any two strictly increasing chains p = p0 ⊂ p1 ⊂ ... ⊂ pn = q of prime ideals are contained in maximal strictly increasing chains from p to q of the same (finite) length. In a geometric situation, in which the dimension of an algebraic variety attached to a prime ideal will decrease as the prime ideal becomes bigger, the length of such a chain n is usually the difference in dimensions.
PHIn chemistry, pH (piːˈeɪtʃ ), also referred to as acidity, historically denotes "potential of hydrogen" (or "power of hydrogen"). It is a scale used to specify the acidity or basicity of an aqueous solution. Acidic solutions (solutions with higher concentrations of hydrogen () ions) are measured to have lower pH values than basic or alkaline solutions. The pH scale is logarithmic and inversely indicates the activity of hydrogen ions in the solution. where [H+] is the equilibrium molar concentration (mol/L) of H+ in the solution.
Polynomial ringIn mathematics, especially in the field of algebra, a polynomial ring or polynomial algebra is a ring (which is also a commutative algebra) formed from the set of polynomials in one or more indeterminates (traditionally also called variables) with coefficients in another ring, often a field. Often, the term "polynomial ring" refers implicitly to the special case of a polynomial ring in one indeterminate over a field. The importance of such polynomial rings relies on the high number of properties that they have in common with the ring of the integers.
