PolyelectrolytePolyelectrolytes are polymers whose repeating units bear an electrolyte group. Polycations and polyanions are polyelectrolytes. These groups dissociate in aqueous solutions (water), making the polymers charged. Polyelectrolyte properties are thus similar to both electrolytes (salts) and polymers (high molecular weight compounds) and are sometimes called polysalts. Like salts, their solutions are electrically conductive. Like polymers, their solutions are often viscous.
Debye lengthIn plasmas and electrolytes, the Debye length (Debye radius or Debye–Hückel screening length), is a measure of a charge carrier's net electrostatic effect in a solution and how far its electrostatic effect persists. With each Debye length the charges are increasingly electrically screened and the electric potential decreases in magnitude by 1/e. A Debye sphere is a volume whose radius is the Debye length. Debye length is an important parameter in plasma physics, electrolytes, and colloids (DLVO theory).
Chain (unit)The chain (abbreviated ch) is a unit of length equal to 66 feet (22 yards), used in both the US customary and Imperial unit systems. It is subdivided into 100 links. There are 10 chains in a furlong, and 80 chains in one statute mile. In metric terms, it is 20.1168 m long. By extension, chainage (running distance) is the distance along a curved or straight survey line from a fixed commencing point, as given by an odometer. The chain has been used for several centuries in England and in some other countries influenced by English practice.
Debye sheathThe Debye sheath (also electrostatic sheath) is a layer in a plasma which has a greater density of positive ions, and hence an overall excess positive charge, that balances an opposite negative charge on the surface of a material with which it is in contact. The thickness of such a layer is several Debye lengths thick, a value whose size depends on various characteristics of plasma (e.g. temperature, density, etc.). A Debye sheath arises in a plasma because the electrons usually have a temperature on the order of magnitude or greater than that of the ions and are much lighter.
Gunter's chainGunter's chain (also known as Gunter's measurement) is a distance measuring device used for surveying. It was designed and introduced in 1620 by English clergyman and mathematician Edmund Gunter (1581–1626). It enabled plots of land to be accurately surveyed and plotted, for legal and commercial purposes. Gunter developed an actual measuring chain of 100 links. These, the chain and the link, became statutory measures in England and subsequently the British Empire.
Contour integrationIn the mathematical field of complex analysis, contour integration is a method of evaluating certain integrals along paths in the complex plane. Contour integration is closely related to the calculus of residues, a method of complex analysis. One use for contour integrals is the evaluation of integrals along the real line that are not readily found by using only real variable methods. Contour integration methods include: direct integration of a complex-valued function along a curve in the complex plane; application of the Cauchy integral formula; and application of the residue theorem.
Double layer (surface science)In surface science, a double layer (DL, also called an electrical double layer, EDL) is a structure that appears on the surface of an object when it is exposed to a fluid. The object might be a solid particle, a gas bubble, a liquid droplet, or a porous body. The DL refers to two parallel layers of charge surrounding the object. The first layer, the surface charge (either positive or negative), consists of ions which are adsorbed onto the object due to chemical interactions.
Particle aggregationParticle agglomeration refers to the formation of assemblages in a suspension and represents a mechanism leading to the functional destabilization of colloidal systems. During this process, particles dispersed in the liquid phase stick to each other, and spontaneously form irregular particle assemblages, flocs, or agglomerates. This phenomenon is also referred to as coagulation or flocculation and such a suspension is also called unstable. Particle agglomeration can be induced by adding salts or other chemicals referred to as coagulant or flocculant.
ElectrolyteAn electrolyte is a medium containing ions that is electrically conducting through the movement of those ions, but not conducting electrons. This includes most soluble salts, acids, and bases dissolved in a polar solvent, such as water. Upon dissolving, the substance separates into cations and anions, which disperse uniformly throughout the solvent. Solid-state electrolytes also exist. In medicine and sometimes in chemistry, the term electrolyte refers to the substance that is dissolved.
Electric-field screeningIn physics, screening is the damping of electric fields caused by the presence of mobile charge carriers. It is an important part of the behavior of charge-carrying fluids, such as ionized gases (classical plasmas), electrolytes, and charge carriers in electronic conductors (semiconductors, metals). In a fluid, with a given permittivity ε, composed of electrically charged constituent particles, each pair of particles (with charges q1 and q2) interact through the Coulomb force as where the vector r is the relative position between the charges.
