AlkeneIn organic chemistry, an alkene is a hydrocarbon containing a carbon–carbon double bond. The double bond may be internal or in the terminal position. Terminal alkenes are also known as α-olefins. The International Union of Pure and Applied Chemistry (IUPAC) recommends using the name "alkene" only for acyclic hydrocarbons with just one double bond; alkadiene, alkatriene, etc., or polyene for acyclic hydrocarbons with two or more double bonds; cycloalkene, cycloalkadiene, etc.
Persistent carbeneA persistent carbene (also known as stable carbene) is a type of carbene demonstrating particular stability. The best-known examples and by far largest subgroup are the N-heterocyclic carbenes (NHC) (sometimes called Arduengo carbenes), for example diaminocarbenes with the general formula (R2N)2C:, where the four R moieties are typically alkyl and aryl groups. The groups can be linked to give heterocyclic carbenes, such as those derived from imidazole, imidazoline, thiazole or triazole.
Chain (unit)The chain (abbreviated ch) is a unit of length equal to 66 feet (22 yards), used in both the US customary and Imperial unit systems. It is subdivided into 100 links. There are 10 chains in a furlong, and 80 chains in one statute mile. In metric terms, it is 20.1168 m long. By extension, chainage (running distance) is the distance along a curved or straight survey line from a fixed commencing point, as given by an odometer. The chain has been used for several centuries in England and in some other countries influenced by English practice.
Gunter's chainGunter's chain (also known as Gunter's measurement) is a distance measuring device used for surveying. It was designed and introduced in 1620 by English clergyman and mathematician Edmund Gunter (1581–1626). It enabled plots of land to be accurately surveyed and plotted, for legal and commercial purposes. Gunter developed an actual measuring chain of 100 links. These, the chain and the link, became statutory measures in England and subsequently the British Empire.
Ring-closing metathesisRing-closing metathesis (RCM) is a widely used variation of olefin metathesis in organic chemistry for the synthesis of various unsaturated rings via the intramolecular metathesis of two terminal alkenes, which forms the cycloalkene as the E- or Z- isomers and volatile ethylene. The most commonly synthesized ring sizes are between 5-7 atoms; however, reported syntheses include 45- up to 90- membered macroheterocycles. These reactions are metal-catalyzed and proceed through a metallacyclobutane intermediate.
Open-chain compoundIn chemistry, an open-chain compound (also spelled as open chain compound) or acyclic compound (Greek prefix "α", without and "κύκλος", cycle) is a compound with a linear structure, rather than a cyclic one. An open-chain compound having no side chains is called a straight-chain compound (also spelled as straight chain compound). Many of the simple molecules of organic chemistry, such as the alkanes and alkenes, have both linear and ring isomers, that is, both acyclic and cyclic, with the latter often classified as aromatic.
