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Toward Knowledge-Based Grain-Boundary Engineering of Transparent Alumina Combining Advanced TEM and Atomistic Modeling

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Paul Bowen, Cécile Hébert, Marco Cantoni, Michael Stuer, Farhang Nabiei, Abhishek Tewari
2015

Abstract

Transition element dopants (e.g., Y, La) are commonly used as sintering aids in polycrystalline alumina ceramics, which segregate to the grain boundaries and control the grain-boundary mobility. However, due to the extremely thin (

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https://infoscience.epfl.ch/entities/publication/d3174586-dbfb-4d44-8401-0d954dc75e90

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Related concepts (21)

In materials science, a grain boundary is the interface between two grains, or crystallites, in a polycrystalline material. Grain boundaries are two-dimensional defects in the crystal structure, and tend to decrease the electrical and thermal conductivity of the material. Most grain boundaries are preferred sites for the onset of corrosion and for the precipitation of new phases from the solid. They are also important to many of the mechanisms of creep.

Sintering or frittage is the process of compacting and forming a solid mass of material by pressure or heat without melting it to the point of liquefaction. Sintering happens as part of a manufacturing process used with metals, ceramics, plastics, and other materials. The nanoparticles in the sintered material diffuse across the boundaries of the particles, fusing the particles together and creating a solid piece.

In materials science, grain growth is the increase in size of grains (crystallites) in a material at high temperature. This occurs when recovery and recrystallisation are complete and further reduction in the internal energy can only be achieved by reducing the total area of grain boundary. The term is commonly used in metallurgy but is also used in reference to ceramics and minerals. The behaviors of grain growth is analogous to the coarsening behaviors of grains, which implied that both of grain growth and coarsening may be dominated by the same physical mechanism.

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