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Publications associées (13)

Enhanced Leaching of Zinc Ferrite by the Formation of a Solid Solution With Magnetite in Hydrochloric Acid Solution

The high zinc and iron contents of electric arc furnace (EAF) dust in the forms of zinc ferrite (ZnFe2O4) and magnetite (Fe3O4) make it a valuable secondary source of these metals. ZnFe2O4 and Fe3O4 are known to form a solid solution at all compositions, a ...

SPRINGER2023

Development of Cyclopentadienylcobalt(III) Catalyzed Asymmetric C-H Functionalizations

Kristers Ozols

Transition metal catalyzed C-H activation plays a major role in modern organic chemistry, affording mild, selective and atom-efficient protocols. Most of current developments in the field rely on the use of several precious metals. As a consequence, an int ...

EPFL2022

Additive manufacturing of a precious bulk metallic glass

Roland Logé, Jamasp Jhabvala, Güven Kurtuldu, Antonia Neels, Navid Sohrabi, Annapaola Parrilli

For the first time, a high-density amorphous and crack-free bulk metallic glass (BMG) based on a precious metal (PdCuNiP) was produced via additive manufacturing (AM). Laser powder-bed fusion (LPBF) was used for the fabrication of the samples, and led to a ...

2021

Shape Engineering of Metal-Organic Frameworks via MOF@Polymer Composite Fabrication

Bardiya Valizadeh

Metal-organic frameworks (MOFs) are a fascinating class of porous materials that have become the subject of research owing to their unique characteristics such as high surface areas, low densities, and structural tunability. Recently, the research has been ...

EPFL2020

Construction of MOF/Polymer Composites for Metal Ion Capture

Daniel Teav Sun

Metal ion capture is of environmental and economic significance. The industrial revolutions have discharged increasing amounts of heavy and precious metals into complex water sources. The key is that these types of metal ions tend to be at trace amounts in ...

EPFL2020

Activation of small molecules promoted by multimetallic complexes supported by redox active ligands

Davide Toniolo

The activation of small molecule is a topic of high current interest. A variety of homogeneous end heterogeneous catalysts have been studied to be able to promote chemical transformation of industrial relevance under mild condition and therefore decrease t ...

EPFL2020

Synthetic methodologies for C-C and C-N bond formation involving alkyl radicals

Guido Barzanò

C-C and C-N bonds are some of the most common structures in molecules ranging from drugs to catalysts and to food additives. Many coupling reactions were developed to form these types of bonds with excellent selectivity and good performance. Still, the syn ...

EPFL2020

Theory of double-kink nucleation in dilute BCC alloys

William Curtin, Alireza Ghafarollahi

Yielding in pure BCC metals and dilute substitutional alloys occurs by double-kink nucleation and propagation along screw dislocations. At low temperatures, the yield stress is controlled by double-kink nucleation. Here, an analytical statistical model is ...

PERGAMON-ELSEVIER SCIENCE LTD2020

Efficient cleavage of aryl ether C–O linkages by Rh–Ni and Ru–Ni nanoscale catalysts operating in water

Paul Joseph Dyson, Vassily Hatzimanikatis, Duncan Thomas Lindsay Alexander, Antoine Philippe Van Muyden, Ning Yan, Georgios Savoglidis, Sviatlana Siankevich, Safak Bulut

Bimetallic Ru–Ni and Rh–Ni nanocatalysts coated with a phase transfer agent efficiently cleave aryl ether C–O linkages in water in the presence of hydrogen. For dimeric substrates with weaker C–O linkages, i.e. α-O-4 and β-O-4 bonds, low loadings of the pr ...

2018

Design of Separated Element Reflector Experiments in CROCUS: PETALE

Andreas Pautz, Vincent Pierre Lamirand, Pavel Frajtag, Mathieu Hursin, Daniel Jerôme Siefman

The present article describes the preliminary design studies for PETALE (Programme d'Etude en Transmission de l'Acier Lourd et ses Elements), an oncoming experimental program in the CROCUS reactor. Within the framework of the Venus-Eole-Proteus collaborati ...

ASTM INTERNATIONAL2018

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