Concept

Auto-assemblage moléculaire

Publications associées (530)

Characterization and Validation of a Novel Robotic System for Fluid-Mediated Programmable Stochastic Self-Assembly

Several self-assembly systems have been developed in recent years, where depending on the capabilities of the building blocks and the controlability of the environment, the assembly process is guided typically through either a fully centralized or a fully ...

Ieee2016

Total Synthesis of Fijiolide A via an Atropselective Paracyclophane Formation

Christoph Heinz

The natural product fijiolide A is a secondary metabolite isolated from a marine-derived actinomycete of the genus Nocardiopsis. It displays inhibitory activity against TNF-Î±-induced activation of NFÎºB, an important transcription factor and a potential t ...

EPFL2016

Giant Hysteresis of Single-Molecule Magnets Adsorbed on a Nonmagnetic Insulator

Harald Brune, François Patthey, Stefano Rusponi, Marina Pivetta, Christian Wäckerlin, Jan Gui-Hyon Dreiser, Fabio Donati, Aparajita Singha, Romana Baltic, Katharina Johanna Diller

TbPc2 single-molecule magnets adsorbed on a magnesium oxide tunnel barrier exhibit record magnetic remanence, record hysteresis opening, perfect out-of-plane alignment of the magnetic easy axes, and self-assembly into a well-ordered layer. ...

Wiley-Blackwell2016

On-Surface Assembly and Reactions of Organic Molecules in Ultra-High Vacuum

Claudius Morchutt

This thesis comprises the study of two types of 2D materials, those stabilized by non-covalent and those by covalent interactions. They are synthesized and studied on well-defined metallic surfaces in ultra-high vacuum (UHV). The self-assembly of terephtha ...

EPFL2016

The Ligand Aspect Ratio as a Decisive Factor for the Self-Assembly of Coordination Cages

Rosario Scopelliti, Kay Severin, Philip Pattison, Euro Solari, Konstantin Zhurov, Suzanne Maria Jansze, Giacomo Cecot, Matthew David Wise, Alba Finelli

It is possible to control the geometry and the composition of metallasupramolecular assemblies via the aspect ratio of their ligands. This point is demonstrated for a series of iron- and palladium-based coordination cages. Functionalized clathrochelate com ...

Amer Chemical Soc2016

Functionalized Dinuclear Clathrochelates as Supramolecular Building Blocks

Mathieu Jérémie Marmier

This thesis details the synthesis and characterization of dinuclear clathrochelates functionalized with groups suitable for supramolecular applications. Their successful incorporation into self-assembled discrete and polymeric structures is related. These ...

EPFL2016

Supramolecular gels based on boronate esters and imidazolyl donors

Rosario Scopelliti, Kay Severin, Nicolas Luisier

Dative boron–nitrogen bonds can be used for the controlled assembly of boronate esters and N-donor ligands. So far, most investigations have focused on crystalline assemblies. In contrast, there are very few reports about soft materials based on dative B–N ...

Royal Society of Chemistry2016

Structure elucidation of a complex CO2-based organic framework material by NMR crystallography

David Lyndon Emsley, Aaron James Rossini, Federico Maria Paruzzo

A three-dimensional structural model of a complex CO2-based organic framework made from high molecular weight, self-assembled, flexible and multi-functional oligomeric constituents has been determined de novo by solid-state NMR including DNP-enhanced exper ...

Royal Soc Chemistry2016

Fluid-Mediated Stochastic Self-Assembly at Centimetric and Sub-Millimetric Scales: Design, Modeling, and Control

Alcherio Martinoli, Massimo Mastrangeli, Felix Stephan Schill, Grégory Mermoud, Bahar Haghighat

Stochastic self-assembly provides promising means for building micro-/nano-structures with a variety of properties and functionalities. Numerous studies have been conducted on the control and modeling of the process in engineered self-assembling systems co ...

MDPI2016

Two-dimensional metal-organic networks as templates for the self-assembly of atom and cluster arrays

Giulia Elisabetta Pacchioni

This thesis presents a study of the use of two-dimensional metal-organic systems as templates for the organization of metal atoms and clusters on surfaces. We start with a systematic characterization of the metal-organic porous networks formed on Cu(111) b ...

EPFL2016

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