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The conversion of 2,2-difluoro-1,3-benzodioxole, an exceptionally acidic arene, via a 4-lithiated intermediate into more than three dozen new derivs. was conceived as a case study. The lithiated species was trapped by C0-electrophiles (4-toluenesulfonyl az ...
We have investigated by angle-resolved photoemission spectroscopy changes induced by Xe adsorption on the spin-orbit-split bands of the epitaxial Ag(111) (root 3x root 3)R30 degrees-Bi surface alloy. We observe an extensive backfolding of the alloy band st ...
A literature method reported for the prepn. of trifluoromethyl substituted benzenes from iodobenzene and congeners was successfully extended to the pyridine series. 2-Iodopyridines can be converted into 2-(trifluoromethyl)pyridines almost quant. by displac ...
Six different fluoroarenes were submitted to the same transformations. Direct deprotonation with alkyllithium or lithium dialkylamide as reagents and subsequent carboxylation afforded acids. These included 2,6-difluorobenzoic acid, 3,6-difluoro-2-iodobenzo ...
We have investigated the doping mechanism of pentacene with iodine and its impact on the structure and on the electronic properties of single crystals, powders, and thin films in a large range of iodine concentration up to six iodine per pentacene (PEN) mo ...
Radial distributions of the total fission rate and the238U- capture-to-total-fission (C 8/F tot) ratio were measured in SVEA-96+ and SVEA-96 Optimal assemblies during the LWR-PROTEUS program. Fission rates predicted using MCNPX with JEFF-3.1 cross sections ...
The safe and economic operation of nuclear power plants (NPPs) requires that the behaviour and performance of the fuel can be calculated reliably over its expected lifetime. This requires highly developed codes that treat the nuclear fuel in a general mann ...
Total fission rate measurements have been performed on full-size BWR fuel assemblies of type SVEA-96+ in the zero power reactor PROTEUS at the Paul Scherrer Institute. This paper presents comparisons of reconstructed 2D pin fission rates from nodal diffusi ...
A systematic comparison between 1,3-difluorobenzene, 1,3-dichlorobenzene, and 1,3-dibromobenzene did not reveal major differences in their behavior towards strong bases such as lithium diisopropylamide or lithium 2,2,6,6-tetramethylpiperidide. Thus, all 2, ...
PCT No. PCT/IB95/00786 Sec. 371 Date Mar. 24, 1998 Sec. 102(e) Date Mar. 24, 1998 PCT Filed Sep. 25, 1995 PCT Pub. No. WO97/12382 PCT Pub. Date Apr. 3, 1997The present invention aims at improving the catalytic activity of the metallic platinum deposited on ...